Badania popiołów pod względem składu petrograficznego, chemicznego i właściwości fizycznych prowadzone są na szeroką skalę i prezentowane w licznych opracowaniach naukowych. Popioły te są pozyskiwane z filtrów i elektrofiltrów zamontowanych w dużych instalacjach przemysłowych. Masowe badanie popiołów pozyskanych bezpośrednio z palenisk rusztowych lub nadmuchowych, zamontowanych w kotłach o niskiej mocy, praktycznie rozpoczęło się dopiero w wyniku walki ze smogiem powstającym wraz z niską emisją. Przy czym pobieranie materiału do badań z palenisk domowych zazwyczaj wiąże się z badaniem ich pod kątem ewentualnego spalania odpadów w kotłach o niskiej mocy. Jest to celowe działanie w przypadku kotłów starego typu, które mogły być zasilane praktycznie dowolnym paliwem. Obecnie na rynku są oferowane piece nowego typu na paliwa dedykowane, w których istnieje możliwość spalania paliw wyłącznie do tych kotłów dostosowanych. Ma to na celu spalanie tylko paliw odnawialnych (z biomasy) lub paliw kopalnych mniej uciążliwych dla środowiska, w założeniu o wysokich parametrach jakościowych, np. ekogroszek, brykiety z węgla brunatnego i torfu. Autorzy opracowania skupili się na przebadaniu popiołu pozyskanego z kotłów przeznaczonych do spalania pelletów drzewnych poprzez wykonanie analizy mikroskopowej pozostałości po spalonej biomasie. Tego typu badanie popiołów dostarcza kompleksowej informacji na temat efektywności procesu spalania, zawartości zanieczyszczeń pozostałych w popiele oraz przydatności popiołu do innych zastosowań. Cały proces od momentu pobrania materiału do badań poprzez wykonanie preparatu i przeprowadzenie analizy trwa do 12 godzin, co zapewnia szybką decyzję o regulacji pieca lub zmianie paliwa. Identyfikacja składników popiołu została opracowana na bazie wyników prac przeprowadzonych przez Grupę roboczą do spraw popiołów lotnych (Komisja III) Międzynarodowego Komitetu ds. Węgla i Petrologii Organicznej – ICCP. Wykazana klasyfikacja została uzupełniona o nowe kluczowe elementy występujące w popiołach powstałych w wyniku spalania pelletów drzewnych w kotłowniach przydomowych. Pozwoliło to na określenie procentowej zawartości charakterystycznych składników występujących w badanym materiale, które stają się swoistym reperem do opiniowania o jakości i sprawności kotła oraz spalanego pelletu.
The article present the results of use of the proposed economic and mathematical apparatus to develop scenarios that provide for the partial or complete elimination of contradictions associated with the pricing policy between oil and gas production and the production of refined products. In the output we noted changes in the material consumption of products of the oil and gas sector of Ukraine. We corrected a certain contradiction between the extractive and processing enterprises of the oil and gas sector. This is related to the uneven distribution of value added between them, which allows extractive enterprises to make a profit, while processing enterprises are at a breakeven point. This situation, as we have seen, also distorts the results of the real assessment of resource efficiency in this sector of the economy. Thus, the research is aimed at developing scenarios that provide for a gradual decrease in the price of extractive products and its simultaneous growth in processing so that the corresponding impact on the economy was minimal. The first scenario envisaged a reduction in the price by –10% for the products of oil and gas companies with a simultaneous increase in the price of refining so that the average share of value added in the country as a whole was not decreased, taking appropriate adjustments of resource efficiency indicators into account. The second scenario was based on the need for deeper price adjustments in the oil and gas sector. Thus, the reduction of the price of products at the extractive enterprises at the level of –20% and its increase it in processing while maintaining the national average share of value added was envisioned. The third scenario provided for the equalization of material consumption in production and processing due to the price factor.
The problem of the migration of metal ions in the environment remains a current problem in light of the quality of obtained crops. The necessity of more and more frequent use of alternative sources of biogens in the form of waste substances, poses a threat of loading significant amounts of metals into the soil – including heavy metals harmful to human health and life. The article discusses a significant problem, namely the comparison of the results of the environmental impact of waste, obtained on the basis of legally authorized leaching tests (three-stage leaching test according to PN-EN 12457:2006), with results obtained from sequential chemical extraction (performed in 4-step chemical extraction developed and recommended in European Union countries by Communities Bureau of References – BCR). The study covered an investigation of industry fly ash from the combustion of lignite, in which Cu, Zn, Cd, Ni, Pb, Cr, Na, K, Li concentrations and loads were calculated. A mobility of analyzed elements was established on this basis. From heavy metals, the highest values in fraction I were noted for nickel and copper and zinc as well as nickel were noted for fraction IV . Peaking values of electrolytic conductivity in eluates was created by high concentrations of macroelements (Na and K). These tests confirm that the leaching tests used for their application in the natural environment indicate such concentrations at the highest levels that can be obtained at the first or second stage of sequential chemical extraction, and thus their proper full environmental impact is not known.
The paper presents an approach to identify the state of fine sands on the basis of shear wave velocity measurement. Large body of experimental data was used to derive formulae which relate void ratio with shear wave velocity and mean effective stress for a given material. Two fine sands which contained 8 and 14% of fines were tested. The soils were tested in triaxial tests. Sands specimens were reconstituted in triaxial cell. In order to obtain predetermined void ratio values covering possible widest range of the parameter representing a very loose and dense state as well, the moist tamping method with use of undercompaction technique was adopted. Fully saturated soil underwent staged consolidation at the end of which shear wave velocity was measured. Since volume control of a specimen was enhanced by use of proximity transducers, representative 3 elements sets (i.e. void ratio e, mean effective stress p’ and shear wave velocity VS) describing state of material were obtained. Analysis of the test results revealed that relationship between shear wave velocity and mean effective stress p' can be approximated by power function in distinguished void ratio ranges. This made possible to derive formula for calculating void ratio for a given state of stress on the basis of shear wave velocity measurement. The conclusion concerning sensitivity of this approach to the fines content was presented.
The arc suppression coil determines whether it can effectively extinguish the arc when it is grounded in the neutral non-effective grounding system. An artificial grounding test is an importantway to verify its performance. In this study, 13 substations with the 10 kV system in the Ningxia areawere selected and considered. Based on the artificial single-phase grounding test, the residual current, the compensation current and the off-resonance degree were measured in the arc suppression coil, and the performance of the arc suppression coil in the 10 kV system was verified. The experimental results show that the error of arc suppression coil automatic measurement is large, the off-resonance degree is large, the resistive component in the compensation current is excessive, the harmonic component exists in the compensating current and capacitive current. To solve these problems, this paper puts forward the corresponding countermeasures for reference.
Moulting southern elephant seals, Mirounga leonina (L.), were counted in 17 discrete wallows at Walker Bay on Livingston Island in the South Shetland Islands between 2 January and 16 February 1994. Daily weather conditions were also recorded. It was also found that, although there were no overall correlations between wind scale, air temperature, sunshine, precipitation, sea roughness and cloud cover with seal numbers, there were conditions on specific days that affected the movements of seals between wallows. Most notably, it was found that numbers of seals decreased when they were exposed to winds, and that they often sought out more sheltered sites nearby.