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Abstract

The disposal of industrial steel mill sludge in landfills has frequently received significant concern as the sludge has a very notable potential to contaminate soil surface and groundwater in the long run. Recently, the incorporation of industrial steel mill sludge into fired clay brick has become one of the promising alternative methods as it could produce a lightweight product while minimizing the environmental impact of the waste used. In this study, fired clay bricks as the most common building material were incorporated with 0%, 5%, 10% and 15% of steel mill sludge and fired at 1050°C (heating rate of 1°C/min). The manufactured bricks were subjected to physical and mechanical properties such as firing shrinkage, dry density, and compressive strength while the Toxicity Characteristic Leaching Procedure (TCLP) was conducted to analyze leaching behavior from the manufactured bricks. The results demonstrated that incorporation up to 15% of steel mill sludge reduces the properties up to 27.3% of firing shrinkage, 8.1% of dry density and 67.3% of compressive strength. The leaching behavior of Zn and Cu from steel mill sludge was reduced up to 100% from 7414 to 9.22 ppm (Zn) and 16436 to 4.654 ppm (Cu) after 15% of sludge incorporation. It was observed that high temperature during the firing process would improve the properties of bricks while immobilizing the heavy metals from the waste. Therefore, recycling steel mill sludge into construction building materials could not only alleviate the disposal problems but also promote alternative new raw materials in building industries.
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Authors and Affiliations

Noor Amira Sarani
1
ORCID: ORCID
Azini Amiza Hashim
1
ORCID: ORCID
Aeslina Abdul Kadir
1
ORCID: ORCID
Nur Fatin Nabila Hissham
1
ORCID: ORCID
Mohd Ikhmal Haqeem Hassan
1
ORCID: ORCID
M. Nabiałek
2
ORCID: ORCID
B. Jeż
2
ORCID: ORCID

  1. Universiti Tun Hussein Onn Malaysia, Faculty of Civil Engineering and Built Environment, 86400 Parit Raja, Batu Pahat, Johor, Malaysia
  2. Department of Physics, Faculty of Production Engineering and Materials Technology, Częstochowa University of Technology, Al. Armii Krajowej 19,42-200 Częstochowa
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Abstract

Photoluminescence of HgCdTe epitaxial films and nanostructures and electroluminescence of InAs(Sb,P) light-emitting diode (LED) nanoheterostructures were studied. For HgCdTe-based structures, the presence of compositional fluctuations, which localized charge carriers, was established. A model, which described the effect of the fluctuations on the rate of the radiative recombination, the shape of luminescence spectra and the position of their peaks, was shown to describe experimental photoluminescence data quite reasonably. For InAs(Sb,P) LED nanoheterostructures, at low temperatures (4.2–100 K) stimulated emission was observed. This effect disappeared with the temperature increasing due to the resonant ‘switch-on’ of the Auger process involving transition of a hole to the spin-orbit-splitted band. Influence of other Auger processes on the emissive properties of the nanoheterostructures was also observed. Prospects of employing II–VI and III–V nanostructures in light-emitting devices operating in the mid-infrared part of the spectrum are discussed.

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Authors and Affiliations

K.D. Mynbaev
A.V. Shilyaev
A.A. Semakova
E.V. Bykhanova
N.L. Bazhenov
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Abstract

The aim of this paper is to study the applicability of the theory of micropolar fluids to modelling and calculating flows in microchannels depending on the geometrical dimension of the flow field. First, it will be shown that if the characteristic linear dimension of the flow becomes appropriately large, the equations describing the micropolar fluid flow can be transformed into Navier-Stokes equations. Next, Poiseuille flows in a microchannel is studied in detail. In particular, the maximal cross-sectional size of the channel for which the micropolar effects of the fluid flow become important will be established. The experimentally determined values of rheological constants of the fluid have been used in calculations.

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Authors and Affiliations

A. Kucaba-Piętal

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