Potential sources of rare earth elements are sought after in the world by many researchers. Coal
ash obtained at high temperatures (HTA ) is considered among these sources.
The aim of the study was an evaluation of the suitability of the high temperature ash (HTA ) formed
during the combustion of bituminous coal from the Ruda beds of the Pniówek coal mine as an
potential resource of REY . The 13 samples of HTA obtained from the combustion of metabituminous
(B) coal were analyzed.
The analyses showed that the examined HTA samples varied in their chemical composition.
In accordance with the chemical classification of HTA , the analyzed ash samples were classified
as belonging to the following types: sialic, sialocalcic, sialoferricalcic, calsialic, fericalsialic,
ferisialic.
The research has shown that the rare earth elements content (REY ) in examined HTA samples
are characterized by high variability. The average REY content in the analyzed ashes was 2.5 times
higher than the world average (404 ppm).
Among rare earth elements, the light elements (LREY ) were the most abundant. Heavy elements
(HREY ) had the lowest share.
A comparison of the content of the individual rare earth elements in HTA samples and in UCC
showed that it was almost 20 times higher than in UCC.
The distribution patterns of REY plotted for all samples within their entire range were positioned
above the reference level and these curves were of the M-H or M-L type. The data presented indicate, that the analyzed ash samples should be regarded as promising REY
raw materials. Considering the fact that in 7 out of 13 analyzed ash samples the REY content was
higher than 800 ppm, REY recovery from these ashes may prove to be economic.
The Neogene basaltoid intrusions found in the S-7 borehole in the Sumina area (USCB) caused transformations of the adjacent Carboniferous rocks. The mineral and chemical compositions of the basaltoides are similar to those of the Lower Silesian basaltoides. The transformations that took place in the vicinity of the intrusion were manifested in the formation of natural coke, the secondary mineralization of these rocks (calcite, chlorite, zeolites and barite) and in the specific distribution of rare earths (REY). Among REY, the light elements (LREY) had the highest share, while the heavy elements (HREY) had the lowest share. Regardless of the lithological type of the analyzed rock, with increasing distance from the intrusion, the percentage of MREY and HREY elements increases at the expense of the light elements LREY. All analyzed distribution patterns of the REYs are characterized by the occurrence of anomalies, which often show a significant correlation with the distance of sampling points from the basaltoid intrusion. The specific distribution of REYs in the vicinity of the intrusion of igneous rocks is an indication of the impact of hydrothermal solutions associated with the presence of basaltoides on the rocks closest to them located at a temperature of over 200°C.
The S-7 borehole log from the Sumina area (USCB Poland) revealed the presence of three basaltic veins
originating from a basalt dyke. Coal interlayers in the rocks surrounding the basaltic veins have been coked to
form natural coke. Photometric measurements revealed that the optical properties of the studied natural coke
samples are characteristic of semi-graphite (Rmax > 9%). The natural coke matrix of all of the analyzed samples
has a biaxial negative optical character. Vitrinite in the examined natural coke samples is characterized by a
lower optical anisotropy than that of the natural matrix and it has a biaxial positive optical character. Vitrinite
in almost all samples taken at locations more distant from the intrusion has a biaxial positive optical character.
A reversal of the changes of the true maximum vitrinite reflectance and bireflectance with changing distance
from the second basaltic vein has been observed. The temperature regime that acted upon the dispersed organic
matter located in the immediate vicinity of the intrusion, estimated on the basis of the selected experimental
data, is suggested to be higher than 750 °C.