The paper discusses the issue of the utilization of selected raw materials obtained as by-products of rock mining and processing in the ceramic industry in Poland. The raw materials in question are: kaolinite-rich clayey substance remaining after quartz sand washing and alkalis-rich finest fractions generated in the course of the production of granite crushed aggregates. Despite usually high content of coloring oxides, they have been utilized for the production of ceramic goods, the high whiteness of which is not required after firing. High interest in these materials was connected with the implementation of the fast firing method as well as modernization and large scale expansion of the domestic ceramic industry, especially ceramic tiles and sanitaryware sectors. Between the mid-1990s and 2018, the annual consumption of kaolinite raw materials being by-products of quartz sand washing increased from ca. 20,000 to 100,000–120,000 Mg. At the same time the sales of secondary granite fractions utilized as a flux in the ceramic industry rose from 30,000 to 120,000 Mg per year in 2007–2008, and 50,000–70,000 Mg per year most recently. The development of the utilization of these raw materials has been an example of the rational and comprehensive management of all the minerals that occur in deposits in operation. This is particularly important in the context of the depletion of these raw materials reserves and the limited availability of their new deposits. Furthermore, this also makes a contribution towards reducing the scale of imports of raw materials for the ceramic tile industry, which is inevitable due to insufficient supplies from domestic sources.
Mineral fillers are mainly utilized in the production of printing and writing papers (P&W) to improve their optical features and their vulnerability to printing. With the high cost of pulp, the aim of their introduction has been to increase mineral loading in paper and reduce the overall cost of production. For many years the only method of paper formation was acid technology, while the only raw material of choice for filling and coating paper and cardboard was kaolin (in the beginning of the 1970s it was 80% of fillers and 94% of coating grades used in Western Europe, while in the USA – 92% and 96%, respectively). The onset on new methods of acid-free (alkaline) paper forming caused a drastic reduction in the kaolin demand for cost-competitive calcium carbonate: GCC – Ground Calcium Carbonate) and PCC – Precipitated Calcium Carbonate. This also resulted from the progressive self-destruction of machine-made acid papers. In 2013, the share of calcium carbonate in the total production of fillers was 83%, while kaolin accounted for 10%, and talc – 7%. The article presents the parameters of principal mineral fillers for the paper industry and the main reasons why they are suitable for particular kinds of paper. Kaolin, due to the platy nature of its main mineral constituent – kaolinite, is preferred in multiple coating papers. The choice of GCC is beneficial because of its low price and properties (especially whiteness). PCC , due to the possibility of shape and particle size modification serves as filler in uncoated woodfree papers, the key features of which are expected to be lightness and opacity. Size distribution is the main difference between PCC and GCC . The article also presents tendencies observed over the last several years in the paper market in Poland, i.e. in a significant growth in coated paper and board for packaging, as well as the decreasing demand for newspaper, which is a consequence of progressive digitalization.