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Abstract

The study presents a comparison of the results of structural tests, impact strength and strength properties of cast iron EN-GJS-400-15, which is produced in industrial conditions and the ductile cast iron, with addition of nickel, in austenitic matrix. Due to the ongoing energy transformation and attempts to inject hydrogen into existing gas grids, gas fittings manufacturers are looking for materials that will be more resistant to the destructive effects of hydrogen than the currently used ductile cast iron. The aim of the work was to obtain cast iron with the addition of nickel (about 20%) with similar strength parameters, better impact strength, both at room temperature and at lower temperatures, as well as a stable austenitic matrix in ductile cast iron. All assumptions were achieved. In the future, research should be undertaken to develop an economically optimal chemical composition, without a significant loss of strength properties, and the resistance of gate valves made of austenitic cast iron to the destructive effects of hydrogen should be examined. The work is preliminary research.
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Bibliography

[1] Kanellopoulos, K., Busch, S., De Felice, M., Giaccaria, S. and Costescu, A. (2022). Blending hydrogen from electrolysis into the European gas grid. EUR 30951 EN, Publications Office of the European Union, Luxembourg, 2022, ISBN 978-92-76-46346-7, DOI:10.2760/908387, JRC 126763.

[2] ToGetAir. (2024). Hydrogen Needs Strong Support. Retrieved December, 18, 2023 from https://raport.togetair.eu/ogien/energia-przyszlosci/wodor-potrzebuje-mocnego-wsparcia. (in Polish).

[3] Jaworski, J., Kukulska-Zając, E. & Kułaga, P. (2019). Selected issue regarding the impact of addition of hydrogen to natural gas on the elements of the gas system. Nafta-Gaz. 10, 625-632. DOI: 10.18668/NG.2019.10.04. (in Polish).

[4] Bąkowski, K, (2007). Gas grids and installations – guide. Warszawa: WNT. (in Polish).

[5] EN 13774:2013 Valves for gas distribution system with maximum operating pressure less than or equal to 16 bar – Performance requirements.

[6] Regulation of the Minister of Economy of April 26, 2013 on the technical conditions to be met by gas grids and their location. (Dz.U z 2013 r., Nr 0, poz. 640). (in Polish).

[7] Information Publication 11/I, Safe use of hydrogen as fuel in commercial industrial applications, Polish Ship Register, Gdańsk 2021, p 36 (in Polish)

[8] Sahiluoma, P., Yagodzinskyy, Y., Forsström, A., Hänninen, H. & Bossuyt, S. (2021). Hydrogen embrittlement of nodular cast iron. Materials and Corrosion. 72(1-2), 245-254. DOI: 10.1002/maco.202011682.

[9] Yoshimoto, T., Matsuo, T. & Ikeda, T. (2019). The effect of graphite size on hydrogen absorption and tensile properties of ferritic ductile cast iron. Procedia Structural Integrity. 14, 18-25. https://doi.org/10.1016/j.prostr.2019.05.004.

[10] Elboujdaini E. (2011). Hydrogen-Induced Cracking and Sulfide Stress Cracking. Uhlig’s Corrosion Handbook. R. Winston Revie (red.). Wiley, 183-194.

[11] Gangloff, R.P. (2012). Gaseous hydrogen embrittlement of materials in energy technologies. Woodhead Publishing.

[12] Jiaxing Liu, Mingjiu Zhao, Lijian Rong (2023). Overview of hydrogen-resistant alloys for high-pressure hydrogen environment: on the hydrogen energy structural materials. Clean Energy. 7(1), 99-115. https://doi.org/10.1093/ce/zkad009.

[13] Dwivedi, S.K. & Vishwakarma. M. (2018). Hydrogen embrittlement in different materials: A review. International Journal of Hydrogen Energy. 43(46), 21603-21616. https://doi.org/10.1016/j.ijhydene.2018.09.201.

[14] Dziadur, W., Lisak, J., & Tabor A. (2004). Corrosion testing of high-nickel ductile cast iron. Journal of Applied Materials Engineering. 6, 28-32. (in Polish).

[15] Guzik, E., Kopyciński, D. (2004). Structure and impact strength of austenitic ductile iron. Archives of Foundry. 4(12), 115-120. ISSN 1642-5308. (in Polish).

[16] Tabor, A., Putyra, P., Zarębski, P. & Maguda, T. (2009). Austenitic ductile iron for low temperature applications. Archives of Foundry Engineering. 9(1), 163-168. ISSN (1897-3310).

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Authors and Affiliations

A. Rączka
1
A. Szczęsny
2
ORCID: ORCID
D. Kopyciński
2
ORCID: ORCID

  1. Fabryka Armatur JAFAR S.A. Kadyiego 12 Street 38-200 Jasło, Poland
  2. AGH University of Science and Technology, Faculty of Foundry Engineering, Reymonta 23, 30-065 Kraków, Poland
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Abstract

Accurate kinetic parameters are vital for quantifying the effect of binder decomposition on the complex phenomena occurring during the casting process. Commercial casting simulation tools often use simplified kinetic parameters that do not comprise the complex multiple reactions and their effect on gas generation in the sand core. The present work uses experimental thermal analysis techniques such as Thermogravimetry (TG) and Differential thermal analysis (DTA) to determine the kinetic parameters via approximating the entire reaction during the decomposition by multiple first-order apparent reactions. The TG and DTA results reveal a multi-stage and exothermic decomposition process in the binder degradation. The pressure build-up in cores/molds when using the obtained multi-reaction kinetic model is compared with the earlier approach of using an average model. The results indicate that pressure in the mold/core with the multi-reaction approach is estimated to be significantly higher. These results underscore the importance of precise kinetic parameters for simulating binder decomposition in casting processes.
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Bibliography

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[5] Grabowska, B., Żymankowska-Kumon, S., Cukrowicz, S., Kaczmarska, K., Bobrowski, A. & Tyliszczak, B. (2019). Thermoanalytical tests (TG–DTG–DSC, Py-GC/MS) of foundry binders on the example of polymer composition of poly(acrylic acid)–sodium carboxymethylcellulose. Joyrnal of Thermal Analysis and Calorimetry. 138(6), 4427-4436. DOI: 10.1007/s10973-019-08883-5.

[6] Kmita, A., Benko, A., Roczniak, A. & Holtzer, M. (2020). Evaluation of pyrolysis and combustion products from foundry binders: potential hazards in metal casting. Jornal of Thermal Analysis & Calorimetgry. 140(5), 2347-2356. DOI: 10.1007/s10973-019-09031-9.

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[12] Zych, J., Mocek, J. & Kaźnica, N. (2018). Kinetics of gases emission from surface layers of sand moulds. Archives of Foundry Engineering. 18(1), 222-226. DOI: 10.24425/118841.

[13] Perondi, D., Broetto, C.C., Dettmer, A., Wenzel, B.M. & Godinho, M. (2012). Thermal decomposition of polymeric resin [(C29H 24N206)n]: Kinetic parameters and mechanisms. Polymer Degradation and Stability. 97(11), 2110-2117. DOI: 10.1016/j.polymdegradstab.2012.08.022.

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[20] Fitzer, E., Schaefer, W. & Yamada, S. (1969). The formation of glasslike carbon by pyrolysis of polyfurfuryl alcohol and phenolic resin. Carbon. 7(6), 643-648. DOI: 10.1016/0008-6223(69)90518-1.

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Authors and Affiliations

Taishi Matsushita
1
ORCID: ORCID
Dinesh Sundaram
1
ORCID: ORCID
Ilja Belov
1
ORCID: ORCID
Attila Dioszegi
1
ORCID: ORCID

  1. Jönköping University, Sweden
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Abstract

The article presents the test results on the technology of surface hardening of castings from unalloyed and low-alloy nodular cast iron using the method of surface heat treatment, i.e., induction surface hardening and methods of thermochemical treatment, i.e. gas nitriding, nitrocarburizing, and nitrocarburizing with oxidation. The scope of research included macro- and microhardness measurements using Rockwell and Vickers methods, respectively, as well as metallographic microscopic examinations using a light microscope. Furthermore, abrasive wear resistance tests were performed using the pin-on-disk method in the friction pair of nodular cast iron – SiC abrasive paper and the reciprocating method in the friction pair of nodular cast iron – unalloyed steel. Analysis of the test results shows that the size and depth of surface layer hardening strongly depend on the chemical composition of the nodular cast iron, determining its hardenability and its ability to create diffusion layers. Medium induction surface hardening made it possible to strengthen the surface layer of the tested nodular cast irons to the level of 700 HV0.5 with a hardening depth of up to approximately 4000μm, while various variants of thermochemical treatment provided surface hardness of up to 750 HV0.5 with a hardening depth of up to approximately 200μm. Furthermore, induction surface hardening increased the resistance to abrasive wear of nodular cast iron castings, depending on the test method, by an average of 70 and 45%, while thermochemical treatment on average by 15 and 60%.
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Bibliography

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[4] Jakobsen, P.D., Langmaack, L., Dahl, F. & Breivik. T. (2013). Development of the soft ground abrasion tester (SGAT) to predict TBM tool wear, torque and thrust. Tunneling and Underground Space Technology. 38, 398-408. DOI:10.1016/j.tust.2013.07.021.

[5] Tiruvenkadam, N., Thyla, P.R. Senthil Kumar, M., Kader, N.A., Pradeep, V.K., Vishnu Kumar, R., Sasikumar, N. (2013). Development of multipurpose reciprocating wear tester under various environmental parameters. In International Conference on Energy Efficient Technologies for Sustainability, 10 – 12 April 2013 (pp. 213 – 216). Nagercoil, India. DOI:10.1109/ICEETS.2013.6533384.

[6] Guanzhang, H., Xiaojing, Y., Yilin, C. & Jie, D. (2011). Development of a system for measuring the variation of friction force on reciprocating wear tester. In Third International Conference on Measuring Technology and Mechatronics Automation, 6-7 January 2011 (Vol. 1, pp. 1045-1049). DOI:10.1109/ICMTMA.2011.262.

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Authors and Affiliations

C. Baron
1
ORCID: ORCID
M. Stawarz
1
ORCID: ORCID
A. Studnicki
1
J. Jezierski
1
ORCID: ORCID
T. Wróbel
1
ORCID: ORCID
R. Dojka
2
M. Lenert
1 2
K. Piasecki
1 2
ORCID: ORCID

  1. Silesian University of Technology, Department of Foundry Engineering, Towarowa 7, 44-100 Gliwice, Poland
  2. Odlewnia RAFAMET Sp. z o.o., ul. Staszica 1, 47-420 Kuźnia Raciborska, Poland

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