The microstructures and mechanical properties of T92 martensitic steel/Super304 austenitic steel weld joints with three welding consumables were investigated. Three types of welding materials ERNiCr-3, ERNiCrCoMo-1and T-304H were utilized to obtain dissimilar welds by using gas tungsten arc weld (GTAW). The results show that heat affect zone (HAZ) of T92 steel consists of coarse-grained and fine-grained tempered martensites. The microstructures of joints produced from ERNiCrCoMo-1 consist of equiaxed dendrite and columnar dendrite grains, which are more complicated than that of ERNiCr-3. In the tensile tests, joints constructed from ERNiCrCoMo-1 and T-304H met the ASME standard. The highest fracture energy was observed in specimens with the welding material ERNiCrCoMo-1. Ni content in weld seam of ERNiCrCoMo-1 was highest, which was above 40%. In conclusion, the nickel alloy ERNiCrCoMo-1 was the most suitable welding material for joints produced from T92 martensitic steel/Super304 austenitic steel.