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Abstrakt

The work presents results of solution combustion method utilization for yttria (Y2O3) nanopowder fabrication. Experiments were carried out with four different reducing agents: urea, glycine, citric acid and malonic acid added in stoichiometric ratio. The reactions were investigated using simultaneous DSC/DTA thermal analysis. After synthesis the reaction products were calcined at temperature range of 800-1100°C and analyzed in terms of particle size, specific surface area and morphology. Best results were obtained for nanoyttria powder produced from glycine. After calcination at temperature of 1100°C the powder exhibits in a form of nanometric, globular particles of diameter <100 nm, according to SEM analysis. The dBET for thus obtained powder is 104 nm, however the powder is agglomerated as the particle size measured by dynamic light scattering analysis is 1190 nm (dV50).
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Autorzy i Afiliacje

M. Gizowska
I. Kobus
K. Perkowski
M. Piątek
G. Konopka
I. Witosławska
M. Osuchowski

Abstrakt

This study attempted to manufacture an Y2O3 ceramic coating layer on a ceramic (AlN) substrate using aerosol deposition (AD) and investigated its macroscopic properties. Pure Y2O3 powder with a polygonal shape and average size of 5.0 μm was used as initial feedstock. Using aerosol deposition with suitable process conditions, an Y2O3 coating layer was successfully fabricated on aluminum nitride (AIN). The thickness of the manufactured coating layer was approximately 10 mm. The coating layer consisted of Y2O3 phase identical to that in the initial powder, and no additional oxides were identified. In regard to the roughness of the Y2O3 coating layer, the average roughness (Ra) measured 1.32 μm, indicating that the surface roughness was relatively even compared to the initial powder size (5 μm). Mechanical properties of the Y2O3 coating layer were measured using nano indentation equipment, and the indentation modulus of the Y2O3 coating layer fabricated by aerosol deposition measured 136.5 GPa. The interface of the coating layer was observed using TEM, and the deposition mechanism of the Y2O3 coating layer manufactured by aerosol deposition was also discussed.

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Autorzy i Afiliacje

D.-Y. Wi
G.-S. Ham
S.-H. Kim
K.-A. Lee

Abstrakt

Y2O3-MgO nanocomposites are one of the most promising materials for hypersonic infrared windows and domes due to their excellent optical transmittance and mechanical properties. In this study, influence of the calcination temperature of Y2O3-MgO nanopowders on the microstructure, IR transmittance, and hardness of Y2O3-MgO nanocomposites was investigated. It was found that the calcination temperature is related to the presence of residual intergranular pores and grain size after spark plasma sintering. The nanopowders calcined at 1000°C exhibits the highest infrared transmittance (82.3% at 5.3 μm) and hardness (9.99 GPa). These findings indicated that initial particle size and distribution of the nanopowders are important factors determining the optical and mechanical performances of Y2O3-MgO nanocomposites.

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Autorzy i Afiliacje

S.-M. Yong
D.H. Choi
K. Lee
S.-Y. Ko
D.-I. Cheong
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Abstrakt

The nano-sized Y2O3 dispersed W composite powder is prepared by ultrasonic spray pyrolysis of a tungsten precursor using ammonium metatungstate hydrate and a polymer addition solution method using Y-nitrate. XRD analysis for calcined powder showed the formation of WO2 phase by partial oxidation of W powder during calcination in air. The TEM and phase analysis for further hydrogen reduction of calcined powder mixture exhibited that the W powder with a uniform distribution of Y2O3 nanoparticles can be successfully produced. These results indicate that the wet chemical method combined with spray pyrolysis and polymer solution is a promising way to synthesis the W-based composites with homogeneous dispersion of fine oxide particles.
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Bibliografia

[1] W.D. Klopp, J. Less-Common Met. 42, 261 (1975).
[2] V. Philipps, J. Nucl. Mater. 415, S2 (2011).
[3] L. Veleva, Z. Oksiuta, U. Vogt, N. Baluc, Fusion Eng. Des. 84, 1920 (2009).
[4] Z. Dong, N. Liu, Z. Ma, C. Liu, Q. Guo, Y. Liu, J. Alloys Compd. 695, 2969 (2017).
[5] C. Ren, Z.Z. Fang, M. Koopman, B. Butler, J. Paramore, S. Middlemas, Int. J. Refract. Met. Hard Mater. 75, 170 (2018).
[6] M.H. Nguyen, S.-J. Lee, W.M. Kriven, J. Mater. Res. 14, 3417 (1999).
[7] S. Yan, J. Yin, E. Zhou, J. Alloys Compd. 450, 417 (2008).
[8] T.R. Wilken, W.R. Morcom, C.A. Wert, J.B. Woodhouse, Met. Trans. B 7, 589 (1976).
[9] S.C. Cifuentes, M.A. Monge, P. Pérez, Corros. Sci. 57, 114 (2012).
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Autorzy i Afiliacje

Hyeonhui Jo
1
Young-In Lee
1 2
ORCID: ORCID
Myung-Jin Suk
3
Young-Keun Jeong
4
ORCID: ORCID
Sung-Tag Oh
1 2
ORCID: ORCID

  1. Seoul National University of Science and Technology, Department of Materials Science and Engineering, Seoul 01811, Republic of Korea
  2. Seoul National University of Science and Technology, The Institute of Powder Technology, Seoul 01811, Republic of Korea
  3. Kangwon National University, Department of Materials Science and Engineering, Samcheok 25913, Republic of Korea
  4. Pusan National University, Graduate School of Convergence Science, Busan 46241, Republic of Korea
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Abstrakt

An optimum route to fabricate the Ni-based superalloy with homogeneous dispersion of Y2O3 particles is investigated. Ni-based ODS powder was prepared by high-energy ball milling of gas-atomized alloy powders and Y2O3 particles treated with a high-pressure homogenizer. Decrease in particle size and improvement of dispersion stability were observed by high-pressure homogenization of as-received Y2O3 particles, presumably by the powerful cavitation forces and by collisions of the particles. Microstructural analysis for the ball-milled powder mixtures reveal that Ni-based ODS powders prepared from high-pressure homogenization of Y2O3 particles exhibited more fine and uniform distribution of Ni and Y elements compared to the as-received powder. These results suggested that high-pressure homogenization process is useful for producing Ni-based superalloy with homogeneously dispersed oxide particles.
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Bibliografia

[1] T.M. Pollock, T. Sammy, J. Propul. Power 22, 361 (2006).
[2] W. Betteridge, S.W.K. Shaw, Mater. Sci. Technol. 3, 682 (1987).
[3] G . Quan, Y. Zhang, P. Zhang, Y. Mai, W. Wang, Trans. Nonferrous Met. Soc. China 31, 438 (2021).
[4] W. Sha, H.K.D.H. Bhadeshia, Metall. Mater. Trans. A 25, 705 (1994).
[5] G .W. Noh, Y.D. Kim, K.-A. Lee, H.-J. Kim, J. Korean Powder Metall. Inst. 27, 8 (2020).
[6] J.S. Benjamin, Metall. Trans. 1, 2943 (1970).
[7] S.K. Kang, R.C. Benn, Metall. Trans. A 16, 1285 (1985).
[8] Y.-I. Lee, E.S. Lee, S.-T. Oh, J. Nanosci. Nanotechnol. 21, 4955 (2021).
[9] J.H. Schneibel, S. Shim, Mater. Sci. Eng. A 488, 134 (2008).
[10] Q.X. Sun, T. Zhang, X.P. Wang, Q.F. Fang, T. Hao, C.S. Liu, J. Nucl. Mater. 424, 279 (2012).
[11] J. Kluge, G. Muhrer, M. Mazzotti, J. Supercrit. Fluids 66, 380 (2012).
[12] O . Mengual, G. Meunier, I. Cayré, K. Puech, P. Snabre, Talanta 50, 445 (1999).
[13] W.D. Pandolfe, J. Dispersion Sci. Technol. 2, 459 (1981).
[14] M. Luo, X. Qi, T. Ren, Y. Huang, A.A. Keller, H. Wang, B. Wu, H. Jin, F. Li, Colloids Surf. A 533, 9 (2017).
[15] C. Suryanarayana, Prog. Mater. Sci. 46, 1 (2001).
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Autorzy i Afiliacje

Jongmin Byun
1
ORCID: ORCID
Young-In Lee
1
ORCID: ORCID
Sung-Tag Oh
1
ORCID: ORCID

  1. Seoul National University of Science and Technology, Department of Materials Science and Engineering & The Institute of Powder Technology, Seoul 01811, Republic of Korea

Abstrakt

Metal fuel is a promising candidate for the pyro-processed nuclear fuel, but the problem of loss of nuclear material due to the high reactivity of metal fuel and melting crucible in the metal fuel casting process must be solved for loss control and waste reduction. In this study, fabrication test was conducted to develop a new material NdYO3 as a new crucible material to improve the degree of anti-reactivity. The NdYO3 compact was manufactured by the CIP (Cold isostatic pressing) method with changing fraction of Nd2O3 and Y2O3 powders. Sintering process was performed at 1550°C for 10 hours. The systematic trends of XRD patterns shows that phase transformations form cubic structure to monoclinic structures occurred with the addition of Y2O3. The rate of pore were discussed with change of fraction of Nd2O3 and Y2O3.
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Autorzy i Afiliacje

Sang-Gyu Park
1
ORCID: ORCID
Ki-Hwan Kim
1
ORCID: ORCID
Jun Hwan Kim
1
ORCID: ORCID

  1. Korea Atomic Energy Research Institute, Next-Generation Fuel Technology Development Division, 989-111, Daedeok-daero, Yuseong-gu, Daejeon, 34057, Republic of Korea

Abstrakt

An optimum route to synthesis the W-based composite powders with homogeneous dispersion of oxide nanoparticles was investigated. The La2O3 dispersed W powder was synthesized by ultrasonic spray pyrolysis using ammonium metatungstate hydrate and lanthanum nitrate. The dispersion of Y2O3 nanoparticles in W- La2O3 powder was carried out by a polymer addition solution method using yttrium nitrate. XPS and TEM analyses for the composite powder showed that the nano-sized La2O3 and Y2O3 particles were well distributed in W powder. This study suggests that the combination processing of ultrasonic spray pyrolysis and polymeric additive solution is a promising way to synthesis W-based composite powders.
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Autorzy i Afiliacje

Youn Ji Heo
1 2
ORCID: ORCID
Eui Seon Lee
1
ORCID: ORCID
Jeong Hyun Kim
1
ORCID: ORCID
Young-In Lee
1 2
ORCID: ORCID
Young-Keun Jeong
3
ORCID: ORCID
Sung-Tag Oh
1 2
ORCID: ORCID

  1. Seoul National University of Science and Technology, Department of Materials Science and Engineering, Seoul 01811, Republic of Korea
  2. Seoul National University of Science and Technology, The Institute of Powder Technology, Seoul 01811, Republic of Korea
  3. Pusan National University, Graduate School of Convergence Science, Busan 46241, Republic of Korea

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