In this study, molten salt electrorefining was used to recover indium metal from In-Sn crude metal sourced from indium tin oxide (ITO) scrap. The electrolyte used was a mixture of eutectic LiF-KF salt and InF3 initiator, melted and operated at 700°C. Voltammetric analysis was performed to optimize InF3 content in the electrolyte, and cyclic voltammetry (CV) was used to determine the redox potentials of In metal and the electrolyte. The optimum initiator concentration was 7 wt% of InF3, at which the diffusion coefficients were saturated. The reduction potential was controlled by applying constant current densities of 5, 10, and 15 mA/cm2 using chronopotentiometry (CP) techniques. In metal from the In-Sn crude melt was deposited on the cathode surface and was collected in an alumina crucible.
This study analysed the influence of montelukast (MON; 10-8 - 10-4 M), a cysteinyl leukotriene receptor 1 (CysLTR1) antagonist, on the contractility of the porcine uterine smooth muscle in the luteal phase of the oesterous cycle (n=8) and in early pregnancy (n=8). Stimulation of uterine strips in the luteal phase with MON has been shown to significantly reduce the amplitude of con- tractions, but not to affect the tension or frequency of contractions. A statistically significant tension increase and decrease in the frequency and amplitude of contractions was observed in pigs in early pregnancy. This suggests that MON has a different effect on the parameters under study in cyclic and pregnant pigs.
An useful electrochemical sensing approach was developed for norepinephrine (NE) detection based on semiconducting polymer (9-nonyl-2,7-di(selenophen-2-yl)- 9H-carbazole) and laccase modified platinum electrode (Pt). The miniature Pt biosensor was designed and constructed via the immobilization of laccase in an electroactive layer of the electrode coated with thin polymeric film. This sensing arrangement utilized the catalytic oxidation of NE to norepinephrine quinone. The detection process was based on the oxidation of catecholamine in the presence of enzyme – laccase. With the optimized conditions, the analytical performance demonstrated selectivity in a wide linear range (0.1–200x10-6 M) with a detection limit of 240 nM and a quantification limit of 365 nM. Moreover, the method was successfully applied for selective NE determination in the presence of interfering substances.
Combustion technology of the coal-water suspension creates a number of new possibilities to organize the combustion process fulfilling contemporary requirements, e.g. in the environment protection. Therefore the in-depth analysis is necessary to examine the technical application of coal as a fuel in the form of suspension. The research undertakes the complex investigations of the continuous coal-water suspension as well as cyclic combustion. The cyclic nature of fuel combustion results from the movement of the loose material in the flow contour of the circulating fluidized bed (CFB): combustion chamber, cyclone and downcomer. The experimental results proved that the cyclic change of oxygen concentration around fuel, led to the vital change of both combustion mechanisms and combustion kinetics. The mathematical model of the process of fuel combustion has been presented. Its original concept is based on the allowance for cyclic changes of concentrations of oxygen around the fuel. It enables the prognosis for change of the surface and the centre temperatures as well as mass loss of the fuel during combustion in air, in the fluidized bed and during the cyclic combustion.
Paper presents the assessment of impact of heat treatment on durability in low-cycle fatigue conditions (under constant load) in castings
made using post-production scrap of MAR-247 and IN-713C superalloys. Castings were obtained using modification and filtration
methods. Additionally, casting made of MAR-247 were subjected to heat treatment consisting of solution treatment and subsequent aging.
During low-cycle fatigue test the cyclic creep process were observed. It was demonstrated that the fine-grained samples have significantly
higher durability in test conditions and , at the same time, lower values of plastic deformation to rupture Δϵpl. It has been also proven that
durability of fine-grained MAR-247 samples can be further raised by about 60% using aforementioned heat treatment.
Electrocatalytic gas sensors belong to the family of electrochemical solid state sensors. Their responses are acquired in the form of I-V plots as a result of application of cyclic voltammetry technique. In order to obtain information about the type of measured gas the multivariate data analysis and pattern classification techniques can be employed. However, there is a lack of information in literature about application of such techniques in case of standalone chemical sensors which are able to recognize more than one volatile compound. In this article we present the results of application of these techniques to the determination from a single electrocatalytic gas sensor of single concentrations of nitrogen dioxide, ammonia, sulfur dioxide and hydrogen sulfide. Two types of classifiers were evaluated, i.e. linear Partial Least Squares Discriminant Analysis (PLS-DA) and nonlinear Support Vector Machine (SVM). The efficiency of using PLS-DA and SVM methods are shown on both the raw voltammetric sensor responses and pre-processed responses using normalization and auto-scaling
cAMP is a second messenger which plays a regulatory role in a wide variety of biological processes in organisms ranging from prokaryotes to higher eukaryotes, but knowledge of its role in macroalgae and vascular plants is limited. We modified cAMP levels in the macroalga Chara vulgaris thallus and studied the effects on thallus growth and gametangia development: db-cAMP (permeable analog of cAMP), adenylate cyclase (AC) activator, forskolin and theophylline (cAMP phosphodiesterase (PDE) inhibitor) were used to elevate cAMP levels, and the AC inhibitors 2'-dAdo and 2'-d3'-AMP were used to decrease them. The results suggest that in Chara vulgaris the cAMP pathway may regulate both vegetative thallus growth and gametangia development, and that these effects may depend on this second-messenger level. Elevated cAMP stimulated thallus growth and delayed gametangia development; decreased cAMP inhibited thallus growth and accelerated maturation of both antheridia and oogonia. These results suggest that the cAMP pathway participates in regulation of developmental processes in Chara vulgaris and that thallus growth and gametangia development require different cAMP levels in cells.
The objective of this paper is to derive the characteristics of an effective governance framework ensuring incentives for conducting a prudent fiscal policy.We study this problem with the use of econometric tools and a sample of 28 European Union Member States between 2003 and 2017. By looking at specific reforms and measures, not only we verify the synthetic effectiveness of fiscal constraints but also we analyse specific elements of the governance framework.Our study shows that fiscal balances are affected not only by the economic cycle, but, among others, by the level of public debt and its cost. We find that the existence of numerical fiscal rules, in that specifically revenue and expenditures rules, their strong legal entrenchment, surveillance mechanisms, sanctions, and flexibility with respect to business cycle have a significant impact on curbing deficits.
The article is an attempted analysis of the literary genre of fable as a case study of a selection of fables by Lyudmila Petrushevskaya. In particular, the analysis focuses on the fable cycles: The New Adventures of Helen the Beautiful, Adventures of Barbie and Wild Animal Fables. The perspective adopted in the article focuses mainly on the axiological aspect of the fables and the reconstruction of their moral message. The moral sense in Petrushevskaya’s fables is veiled under their overt sense. Even the overt sense is hidden deeply under the multiple levels of “intertextual irony” (Eco). The analysis also explores the links between Petrushevskaya’s works, folk magical fairy tales and the prototypical genre of the classical Russian fable. The innovative fables created by Petrushevskaya de-conventionalize the classical schemata of the genre, and as such they constitute an ironic, mocking and sometimes a bitter commentary on the contemporary world. The fables exhibit a high degree of “poetics of everyday life” – a merger of popular and high culture. They both recreate and at the same time mock the schemata and rituals of pop culture, also displaying noticeable feminist tones. In their poetics, the fables employ cyclic and serial arrangement, and are completed with “words of wisdom” that are far from naïve moral judgements.
This paper presents the results of experimental studies and numerical simulations of the ratcheting for the PA6 aluminum. In the initial determination of the material hardening parameters, the samples were subjected to the symmetrical strain-controlled cyclic tension-compression test. The experimental stress-strain curve was compared with the numerical one obtained for non-linear Frederick-Armstrong and Voce models. For better fitting of both curves, the optimization procedure based on the least-square method and the fuzzy logic was applied. After establishing the hardening parameters, numerical simulations of the ratcheting were made. The boundary value problem was solved by means of discrete analysis. The data (force and displacement) obtained in numerical computations were used to control the ratchetting experiment. The results of experiments and numerical calculations were compared. Good convergence proves the reliability of the determination of material hardening data.
Recently, transition metal oxides, which exhibit favorable catalytic abilities, have also been investigated as a material for the detection of hydrazine (N2H4). It has been reported that mixed metal oxides usually offer a higher electrochemical activity than binary oxides. In this work, a TiO2–Fe2O3 coupled system is presented as an enhanced material with major applications in electrochemical detectors. The electrochemical behavior of glassy carbon electrodes modified with TiO2–Fe2O3 in the absence and presence of hydrazine was evaluated via cyclic voltammetry (CV). Experimental results also suggest that the formation of the TiO2– Fe2O3 coupled system enhances electrochemical catalytic performance in N2H4 detection. The modification TiO2 + 2 mol% Fe2O3 provides good analytical performance of detection (0.13 mM) and quantification limits (0.39 mM). The presented coupled system provides the premise for a suitable material for a stable and sensitive N2H4 sensor.