Pulse electrochemical machining (PECM) provides an economical and e.ective method for machining high strength, heat-resistantmaterials into complex shapes such as turbine blades, die, molds and micro cavities. Pulse Electrochemical Machining involves the application of a voltage pulse at high current density in the anodic dissolution process. Small interelectrode gap, low electrolyte .ow rate, gap state recovery during the pulse o.-times lead to improved machining accuracy and surface .nish when compared with ECM using continuous current. This paper presents a mathematical model for PECM and employs this model in a computer simulation of the PECM process for determination of the thermal limitation and energy consumption in PECM. The experimental results and discussion of the characteristics PECM are presented.
The paper presents a proposal of using additional statistical parameters such as: standard deviation, variance, maximum and minimum increases of the observed value that were determined during measurements of temperature fields created on the surface of the tested electrochemical capacitor. The measurements were carried out using thermographic methods in order to support assessment of the condition of electrochemical capacitor under classic durability tests based on methods of determination of capacity and equivalent series resistance. The possibility of using some statistical parameters in assessment of the electrochemical capacitor quality was illustrated. The applied measurement methodology and the results of research associated with the classic methods of supercapacitors’ assessment are presented. The obtained results indicate that the variability of some statistical parameters of temperature fields can be directly related to changing the values of standard parameters describing electrochemical capacitor, which are capacitance and equivalent series resistance.
The machining technology of electrochemical micromachining with ultra short voltage pulses (μPECM) is based on the already well-established fundamentals of common electrochemical manufacturing technologies. The enormous advantage of the highest manufacturing precision underlies the fact of the extremely small working gaps achievable through ultra short voltage pulses in nanosecond duration. This describes the main difference with common electrochemical technologies. With the theoretical resolution of 10 nm, this technology enables high precision manufacturing.
In the present study, the corrosion behaviour of A356 (Al-7Si-0.3Mg) alloy in 3.5% NaCl solution has been evaluated using
cyclic/potentiodynamic polarization tests. The alloy was provided in the unmodified form and it was then modified with AlTi5B1 for grain
refinement and with AlSr15 for Si modifications. These modifications yield to better mechanical properties. Tensile tests were performed.
In addition, bifilm index and SDAS values were calculated and microstructure of the samples was investigated. As a result of the corrosion
test, the Ecorr values for all conditions were determined approximately equal, and the samples were pitted rapidly. The degassing of the
melt decreased the bifilm index (i.e. higher melt quality) and thereby the corrosion resistance was increased. The lowest corrosion rate was
founded at degassing and as-received condition (3.9x10-3 mm/year). However, additive elements do not show the effect which degassing
process shows.
In this study, the corrosion properties of Ti-6Mo-6V-5Cr-3Sn-2.5Zr alloy were investigated as a function of the cold rolling ratio and annealing temperature. The annealing treatment was carried out at temperature of 680°C, 730°C, and 780°C. The highest corrosion potential observed in the specimen with a 10% rolling ratio was 179 mV, which was more positive than that of the non-rolled specimen (–0.214 Vssc). The lowest corrosion current density (1.30×10–8 A/cm2) was observed in the non-rolled specimen which suggested that the integrity of its passive oxide layer was superior to that of the cold-rolled specimens. Time-dependent EIS evaluation revealed that the consistency of the passive oxide layer was highly affected by the subjected rolling ratio over time.
This paper deals with the effect of impeller shape on off-bottom particle suspension. On the basis of numerous suspension measurements, correlations are proposed for calculating the just-suspended impeller speed for a standard pitched four-blade turbine and three types of hydrofoil impellers produced by TECHMIX for several particle sizes and for a wide range of particle concentrations. The suspension efficiency of the tested impellers is compared with the efficiency of a standard pitched blade turbine on the basis of the power consumption required for off-bottom suspension of solid particles. It is shown that the standard pitched blade turbine needs highest power consumption, i.e. it exhibits less efficiency for particle suspension than hydrofoil impellers produced by TECHMIX.
Cast stainless steel of the Cr-Ni duplex type is used, among others, for the cast parts of pumps and valves handling various chemically
aggressive media. Therefore, the main problem discussed in this article is the problem of abrasion wear resistance in a mixture of SiC and
water and resistance to electrochemical corrosion in a 3% NaCl- H2O solution of selected cast steel grades, i.e. typical duplex cast steel,
high silicon and manganese duplex cast steel, and Cr-Ni austenitic cast steel (type AISI 316L). The study shows that the best abrasion
wear resistance comparable to Ni-Hart cast iron was obtained in the cast duplex steel, where Ni was partially replaced with Mn and N.
This cast steel was also characterized by the highest hardness and matrix microhardness among all the tested cast steel grades. The best
resistance to electrochemical corrosion in 3% NaCl- H2O solution showed the cast duplex steel with high content of Cr, Mo and N. The
addition of Ni plays rather insignificant role in the improvement of corrosion resistance of the materials tested.
This paper presents a voltammetric segmented voltage sweep mode that can be used to identify and measure heavy metals' concentrations. The proposed sweep mode covers a set of voltage ranges that are centered around the redox potentials of the metals that are under analysis. The heavy metal measurement system can take advantage of the historical database of measurements to identify the metals with higher concentrations in a given geographical area, and perform a segmented sweep around predefined voltage ranges or, alternatively, the system can perform a fast linear voltage sweep to identify the voltammetric current peaks and then perform a segmented voltage sweep around the set of voltages that are associated with the voltammetric current peaks. The paper also includes the presentation of two auto-calibration modes that can be used to improve system's reliability and proposes the usage of a Gaussian curve fitting of voltammetric data to identify heavy metals and to evaluate their concentrations. Several simulation and experimental results, that validate the theoretical expectations, are also presented in the paper.
The corrosion inhibition behaviour of 1-Ethyl-3-methylimidazolium-methanesulphonate (EMIM[MS]) and 1-Ethyl-3-methylimidazolium acetate (EMIM[Ac]) on API 5L X-52 carbon steel in 2 M HCl was investigated using weight loss, potentiodynamic polarization and electrochemical impedance methods. The corrosion rates of carbon steel decreased in the presence of these ionic liquids. The inhibition efficiencies of the compounds increased with concentration and showed a marginal decrease with a 10°C increase in temperature. Polarization studies showed the compounds to be mixed type inhibitors with stronger anodic character. The adsorption mechanism of both compounds on the metal surface was via physical adsorption and the process obeyed the El-Awardy kinetic-thermodynamic model. The associated activation energy of corrosion and other thermodynamic parameters were calculated to elaborate on the thermodynamics and mechanism of the corrosion inhibition process. EMIM[MS] was found to inhibit the corrosion of carbon steel better than EMIM[Ac] and is attributed to the presence of the highly electronegative sulphur atom in its structure and its larger molecular size.
Nifedipine, a pyridine derivative was investigated as corrosion inhibitor for API 5L X-52 steel in 2 M HCl solution by potentiodynamic polarization, electrochemical impedance spectroscopy and quantum chemical calculations. Statistical tools were used to compare results of the experimental methods. The results showed that nifedipine is capable of inhibiting the corrosion of API 5L X-52 steel in 2 M HCl solution. Potentiodynamic polarization results reveal that nifedipine functions as a mixed-type inhibitor and presents an inhibition efficiency of about 78% at 500 ppm. Impedance data reveal an increasing charge transfer resistance with increasing inhibitor concentration and also shows comparable inhibition efficiency of about 89-94% at 500 ppm. Thermodynamic parameters imply that nifedipine is adsorbed on the steel surface by a physiochemical process and obeys Langmuir adsorption isotherm. The calculated molecular properties namely the highest occupied molecular orbital energy, lowest unoccupied molecular orbital energy, chemical hardness, energy gap, dipole moment, electronegativity and global nucleophilicity index all show a positive relationship to the observed corrosion inhibition efficiency.
Al2Cu phase has been obtained by melting pure metals in the electric arc furnace. It has been found that the intermetallic phase undergoes selective corrosion in the H3PO4 aqueous solutions. Aluminium is dissolved, the surface becomes porous and enriched with copper. The corrosion rate equals to 371 ± 17 g·m–2·day–1 (aerated solution) and 284 ± 9 g·m–2·day–1 (deaerated solution). The surface of Al2Cu phase after selective corrosion was characterised by using electrochemical impedance spectroscopy. It was found that the surface area of the specimens increases with temperature due to higher corrosion rate and is between 2137 and 3896 cm2.