This paper proposes a mathematical model that allows expanding the scope of research into the mechanism of heat transfer during explosive boiling, cavitation and boiling of multicomponent liquids, identifying the most influential factors and optimizing technological processes. The proposed model takes into account the processes of heat accumulation in the high-boiling part of liquid mixtures (for example, emulsions) and the use of this energy in the process of boiling their thermolabile part, as well as for superheating the resulting steam in steam bubbles. This effect can also be used to evaluate the effects of liquid boiling in thermodynamically unstable regions of liquid media.