Spalanie odpadów komunalnych w domowych piecach to problem, z którym boryka się wiele polskich samorządów. Zarządzanie procesami zwalczania i zapobiegania tym zjawiskom jest niezwykle trudne, ponieważ przepisy prawne oraz wymagania jednostek samorządu terytorialnego są niejednoznaczne. Kolejnym istotnym problemem jest stosowanie różnego rodzaju dodatków do paliw stałych. Często dodatki te, pomimo wysokich walorów energetycznych, nie powinny zostać poddane procesowi spalania przez indywidualnych użytkowników z powodu warunków technicznych procesu spalania w indywidualnych urządzeniach grzewczych. Z punktu widzenia użytkownika przy obowiązujących uwarunkowaniach prawnych nie ma możliwość zweryfikowania składu paliwa na etapie zakupu. Podjęta w artykule tematyka wskazuje na przyczyny zjawiska i podkreśla potrzeby wdrożenia modelu identyfikacji. W pracy szczegółowo omówiono diagnozę aktualnej sytuacji w zakresie interesariuszy przedsięwzięcia z uwzględnieniem ich potrzeb, oczekiwań przy uwzględnieniu obowiązujących przepisów prawnych. W artykule wskazano możliwości w zakresie potencjalnych technik identyfikacji domieszek w materiałach opałowych, co pozwoli uzyskać skuteczne narzędzie jednoznacznie określające skład i czystość materiału opałowego oraz co istotniejsze produkty ich spalania. Ponadto przeanalizowano techniki umożliwiające weryfikację spalania i/lub współspalania odpadów komunalnych przez indywidualne urządzenia grzewcze, podkreślając wybrane modele koncepcji. W pracy wskazano na istotny element wdrożenia, którym jest ocena skuteczności. Zakłada się, iż z punktu widzenia założonego celu i przeprowadzonej analizy otoczenia wdrożenia zarówno po stronie interesariuszy, jak i wymagań prawnych, zaproponowany model koncepcji będzie skutecznym elementem poprawy jakości powietrza w zakresie eliminacji procederu nielegalnego spalania, termicznego przekształcania odpadów komunalnych przez użytkowników palenisk domowych oraz wskazania, czy paliwo stałe stosowane do spalania nie stanowi mieszaniny paliwa legalnego z dodatkami nieznanego pochodzenia.
An attempt to summarize the primary iron raw materials and steel market’s hundred years history as well as influence of economic indicators on the iron ore deposit qualification for extraction has been undertaken in the paper. Steel products are crucial to the world economy, and their production has a major impact on the environment. The main factor is the huge scale of the production and growth rate, unprecedented among minerals. Iron ore and concentrates production has increased more than thirty times over the past century, and the geological resource base at the current level of consumption has provided almost 250 years of sufficiency. There have been tremendous changes in the world geography of the ore and steel industry. The iron ore mining industry is the driver of other economic activities (land transport, freight, metallurgy) and involves huge capital and human resources. The consumption of iron raw materials is also considered as an important indicator of the countries development and current or even future economic situation. Population growth remains one of the key stimulating factors. The prices of ore and iron concentrates depend on the quality of the raw material, delivery conditions, market balance and the weight of the ordered cargo. They are usually the subject of negotiations. In the past, they were long-term contracts, while short-term (yearly, quarterly) and current spot transactions are now significant. The prices of ores and concentrates in relation to steel prices are showing a strong correlation. The average iron content of the reserves has been reduced in the largest producers in the 21st century, however it does not translate into the quality of mining output. Exploitation of the richer parts of the mineral deposit is usually carried out. The high content of iron in the output is a response to the technological requirements of the metallurgy where the blast furnace charge should contain at least 56% Fe and 5–8% FeO. The current surplus of geological-mining supply (large resource base) justifies that a mineral deposit choice, destined for excavation, is economic profit maximization as well as social and environmental considerations.
The issue of mercury emission and the need to take action in this direction was noticed in 2013 via the Minamata Convention. Therefore, more and more often, work and new law regulations are commencing to reduce this chemical compound from the environment. The paper presents the problem of removing mercury from waste gases due to new BREF/BAT restrictions, in which the problem of the need to look for new, more efficient solutions to remove this pollution was also indicated. Attention is paid to the problem of the occurrence of mercury in the exhaust gases in the elemental form and the need to carry out laboratory tests. A prototype installation for the sorption of elemental mercury in a pure gas stream on solid sorbents is presented. The installation was built as part of the LIDER project, financed by the National Center for Research and Development in a project entitled: “The Application of Waste Materials From the Energy Sector to Capture Mercury Gaseous Forms from Flue Gas”. The installation is used for tests in laboratory conditions in which the carrier gas of elemental mercury is argon. The first tests on the zeolite sorbent were made on the described apparatus. The tested material was synthetic zeolite X obtained as a result of a two-stage reaction of synthesis of fly ash type C with sodium hydroxide. Due to an increase, the chemical affinity of the tested material in relation to mercury, the obtained zeolite material was activated with silver ions (Ag+) by an ion exchange using silver nitrate (AgNO3). The first test was specified for a period of time of about 240 minutes. During this time, the breakthrough of the tested zeolite material was not recorded, and therefore it can be concluded that the tested material may be promising in the development of new solutions for capturing mercury in the energy sector. The results presented in this paper may be of interest to the energy sector due to the solution of several environmental aspects. The first of them is mercury sorption tests for the development of new exhaust gases treatment technologies. On the other hand, the second aspect raises the possibility of presenting a new direction for the management and utilization of combustion by-products such as fly ash.
Steel and cast-iron products, due to their low price and beneficial properties, are the most widely used among metals; their consumption has become an indicator of the economic development of countries. The characteristics of iron raw materials, in relation to current metallurgical requirements, are presented in the present this article. The globalization of the trade and development of steelmaking technologies have caused significant changes in the quality of raw materials in the last half-century forcing improvements in processing technologies. In many countries, standard concentrates (at least 60% Fe) are almost twice as rich as those processed in the mid-20th century. Methods of quality assessment have been improved and quality standards tightened.
The quality requirements for the most important raw materials ‒ iron ores and concentrates, steel scrap, major alloy metals, coking coal, and coke, as well as gas and other energy media ‒ are reviewed in the present paper. Particular attention is paid to the quality testing methodology. The quality of many raw materials is evaluated multi-parametrically: both chemical and physical characteristics are important. Lower-quality parameters in raw materials equate to significantly lower prices obtained by suppliers in the market.
The markets for these raw materials are diversified and governed by separate sets of newly introduced rules. Price benchmarks (e.g. for standard Australian metallurgical coal) or indices (for iron concentrates) apply. Some raw materials are quoted within the framework of the commodity market system (certain alloying components and steel scrap). The abandonment of the long-established system of multi-annual contracts has led to wide fluctuations in prices, which have reached a scale similar to that of other metals.
The environment is the greatest good for the people. Everyone wants to breath air of the best possible quality, whether living in the city center of a metropolis or in a rural area. Air polluted with very fine particles contribute to the negative effect on people’s health and the whole environment. A significant part of air dust pollution comes from the so-called low emissions sources which include: non-standard furnaces, fireplaces, low-efficiency outdated boilers and local heat sources. Since the beginning of Polish Mining Group’s existence, the company actively participates and supports many activities, the aim of which is to improve the air quality by producing and supplying high quality coal for the residential sector. The company has undertaken pro-ecological activities towards creating a new, pro-ecological strategy as well as product offer. The production of an ecological coal assortment is systematically developing but new coal products are also being launched on the market. One of the company’s priorities is the production of thermal coal for the residential sector. Many organizational and technological changes have been made In that area (e.g. the establishmsnt of the Eco-Fuels Production Plant) to ensure a suitable level of production of the highest quality thermal coal.
Heating of steel or structural aluminum alloys at a speed of 2 to 50 K/min – characterizing the fire conditions – leads to a reduction in mechanical properties of the analyzed alloys. The limit of proportionality fp, real fy and proof f₀₂ yield limit, breaking strength fu and longitudinal limit of elasticity E decrease as the temperature increases. Quantitative evaluation of the thermal conversion in strengths of structural alloys is published in Eurocodes 3 and 9, in the form of dimensionless graphs depicting reduction coefficients and selected (tabulated) discrete values of mechanical properties. The author’s proposal for an analytical formulation of code curves describing thermal reduction of elasticity modulus and strengths of structural alloys recommended for an application in building structures is presented in this paper.