Chalcedonite is a diatomaceous sedimentary rock, which, on account of a very small occurrence area, is included into a group of unique rocks. It occurs at Dęborzynka, Gapinin, Lubocz and Teofilów deposits, located on the Rawska Plateau in the region of Tomaszów Mazowiecki and Nowe Miasto. The deposit in Teofilów is the only documented one and it is now being exploited. The surface of this deposit is 577 437 m2 and its geological resources were determined to be 21.587 - 106 kg (21 587.0 thousand tones). The main component of this rock is chalcedon (69.0-96.6 vol.%), however quartz, opal, iron hydroxides, pyrite, manganese compounds and clay minerals occur in small quantities. The active surface of chalcedonite is relatively small and it was determined as 3-6 m2/g. Chalcedonite had a mesoporous structure of a significantly high pore homogeneity, and the total volume of these pores was 0.03-0.04 cm3/g. On account of its small spatial distribution chalcedonite is a unique rock, which has multi-resource properties. It is useful for manufacturing perlite-like material, crystobalite, wollastonite and mullite. It was also found to be a valuable raw material for the production of pastes, scouring powders, grinder tools and also as good filler for the production of : paints, varnishes, enamel ware, lute and putty materials. Because of its mesoporous structure and due to extended outer surface of the grains, chalcedonite is utilized in water treatment technology, mostly as an effective filtration material. A high usefulness of chalcedonite bed for manganese and iron removal from water shows mostly the presence of a low height of iron removal zone in the filter, and it is also manifested by a relatively short time of introduction into effective manganese(II) removal, as well as by good hydraulic properties of the material, which enable to achieve high mass capacities of the filter and to reach long filtration cycles. Chalcedonit is a very good carrier of manganese oxides and its surface modification of leads to the creation of chemically active bed, which enables removal of manganese(II) from water with high efficiency and without the introduction process. Chalcedonite bed effective removes of ammonia nitrogen from the water in the process of nitrification and waste water treatment. Chalcedonite can be also taken into account as a sorbent for the removal of oil spills.
System Dynamics is methodology for modeling and analyzing complex systems. Such systems can be characterized by interconnectedness and feedback. Applying risk assessment to the results of System Dynamics models is a challenge. Though in some cases the resulting time series data generated by a simulation may appear approximately random at a specific scale, there is often a high-degree of auto-correlation within the data series due to the deterministic nature of generation and feedback loops inherent in the system. This paper presents proposed Dynamic Risk Assessment Method (DRAM) that allows for the estimation of risk for system dynamics data series that appear to be approximately random. DRAM is based on standard risk assessment methods and is simple both to calculate and apply. In this article, the proposed method is applied to determine the risk connected with hypothetical costs of illness stemming from water supply system contamination with Cryptosporidium.
During the past several years big changes have been observed in waste water disposal, noticeable particularly in the improvement of water protection and sewage treatment. An important element of waste water disposal still requiring improvement is a low development of sewage systems in rural and urban areas. The main problem is an increasing amount of sludge, high degree of sediment hydration and considerable ability to anaerobic decomposition, a lack of areas for managing sediments near big cities and deposits of sediments on storage areas. Selected issues of waste water disposal and sludge handling in the Mazovian Province against a background of waste water disposal and sludge handling in Poland were presented in the article.
The results from the experimental research are presented in the abstract. The experimental research involved utilization of the sludge from the mine water treatment plant of Coal Quarry ČSA/Czechoslovak Army/ (hereinafter “ČSA”) and Coal Quarry Jana Švermy (hereinafter “JŠ”) in the segment of thermal insulation mortars. The mine water treatment is described below including chemical and mineralogical sludge composition as the additional component of the binding material in the polyurethane thermal insulation mortars. Furthermore the composition of experimental mixtures of the thermal insulation polyurethane mortar is presented in the work and its physical-mechanical properties. The monitored elements included the strength characteristics, heat conductivity coefficient λ, and water vapour diffusion coefficient μ.
The paper describes the effectiveness of mycoestrogen removal in an integrated ozonation - nanofiltration system for water treatment. The results were compared to those obtained for ozonation and nanofiltration carried out as single processes. It has been found that the effectiveness of mycoestrogen removal in the integrated system was higher than that observed for single ozonation. During ozonation, the removal of micropollutants was affected by the dose of an oxidizing agent and type of treated water. As far as nanofiltration is concerned, its effectiveness both in the integrated system and as a single process was similar. Nevertheless, it is advisable to precede nanofiltration with ozonation because of membrane efficiency.
The article describes problems related to intensification of energy production at a sewage treatment plant. The authors analyze anaerobic co-digestion of sludge from a water treatment plant and sewage treatment plant. The authors proposed a methodology of the research and analyzed the preliminary results, which showed that co-digestion of sewage and water sludge enhanced biogas production. The authors hope that the results of the study will provide a basis for development of methodology for sludge control and disposal.
The aim of the study was to analyze and assess the possibility of using a two-stage filtration system with ceramic membranes: a 3-tube module with 1.0 kDa cut-off (1st stage) and a one-tube module with 0.45 kDa cut-off (2nd stage) for treating effluent water from a juvenile African catfish aquaculture. The study revealed that during the 1st filtration stage of the effluent water, the highest degrees of retention were obtained with respect to: suspended solids SS (rejection coefficient RI=100%), turbidity (RI=99.40%), total iron (RI=89.20%), BOD5 (RI=76.0%), nitrite nitrogen (RI=62.30%), and CODCr (RI=41.74%). The 2nd filtration stage resulted in a lower reduction degree of the tested indicators in comparison to the 1st filtration stage. At the 2nd stage, the highest values of the rejection coefficient were noted in for the total iron content (RIV=100%), CODCr (RIV=59.52%; RV=64.28%, RVI=63.49%) and turbidity (RIV and RV = 45.0%, RVI=50.0%). The obtained results indicate that ceramic membranes (with 1.0 and 0.45 kDa cut-offs) may be used in recirculation aquaculture systems as one of the stages of effluent water treatment.
In this study, the synthesis of copper-based multi-walled carbon nanotube composites is described. Over the last years, carbon nanotubes (CNTs) have been widely used in many scientific research fields and have found applications in several sectors, e.g. for water treatment. This work focuses on combining the exceptional characteristics of CNTs, such as high specific surface area and antibacterial properties, with the antimicrobial/ antivirus features of copper oxides. The influence of synthesis parameters and thermal treatment on the final product was studied. Copper leakage was evaluated at both pH 5 and pH 7, confirming the possibility of applying Cu-based MWCNT composites in water filtration systems.
Throughout the world, considerable quantities of water treatment sludge (WTS) and sewage sludge (SS) are produced as waste. This study assessed in the laboratory, the possibility to use both waste products when they are incorporated as filler at 1% with relation to the total mass of a hot mix asphalt - HMA. To this end, both waste products were initially reduced to ash through a calcination process. Resistance tests under monotonic load (Marshall and indirect tension tests), and cyclic load (resilient modulus test) were applied on mixes that contained WTS and SS. Besides, moisture damage (modified Lotmman test), and abrasion (Cantabro) resistance were assessed. An analysis of variance (ANOVA) test was performed in order to verify if the results are statically equal or not to those of the control HMA. As a general conclusion, it is reported that both materials show a resistance increase under monotonic load and higher stiffness under cyclic load (cohesion) when they are incorporated into the mix as filler despite the fact that the asphalt content used was less than the control mix. However, some problems are observed associated with moisture damage resistance, and friction wear (adherence).
In the study, particle size distribution of the MIEX® resin was presented. Such analyses enable to determinate whether presence of fine resin fraction may be the reason for unfavorable membrane blocking during water purification by the hybrid MIEX®DOC – microfiltration/ultrafiltration systems. Granulometric analysis of resin grains using the laser diffraction particle size analyzer (laser granulometer) was carried out as well as the microscopic analysis with scanning electron microscope. The following samples were analyzed: samples of fresh resin (a fresh resin – not used in water treatment processes) and samples of repeatedly used/regenerated resin that were collected to analysis during mixing and after sedimentation process. Particle size distribution was slightly different for fresh resin and for repeatedly used/regenerated resin. The grains sizes of fresh resin reached approximately 60 μm (d10), 120 μm (d50) and 220 μm (d90). Whereas the sizes of repeatedly used/regenerated resin were about 15 μm (d10), 40 μm (d50) and 115-130 μm (d90). The smallest resin grains sizes were in the range of 0.3-0.45 μm. This ensures that the ultrafiltration membranes retain all resin grains, even the smallest ones. Whereas the microfiltration membranes must be appropriately selected to guarantee full separation of the resin grains and at the same time to exclude a membrane pores blocking.
Arsenic is one of the most harmful pollutants in groundwater. In this paper, the Nepali bio sand filter (BSF) was modi-fied with different bio-adsorbents, and proved to be an efficient method for arsenic removal from groundwater. Three dif-ferent bio-adsorbents were used to modify the Nepali BSF. Iron nails and biochar BSF, ~96% and ~93% arsenic removal was achieved, within the range of WHO guidelines. In iron nails, BSF and biochar BSF ~15 dm3∙h–1 arsenic content water was treated. In the other two BSFs, rice-husk and banana peel were used, the arsenic removal efficiency was ~83% of both BSFs. Furthermore, the efficiency of rice-husk and banana peel BSFs can be increased by increasing the surface area of the adsorbent or by reducing the flow rate.
Our scientific research is based on oxidation reactions and monitoring of chemical reaction kinetics in the Velekinca groundwaters plant in Gjilan municipality, Kosovo. The GW of this plant contains high concentration of manganese so we need to use potassium permanganate (KMnO4) as one of the most power oxidants in the water treatment plant. In our re-search the high concentration of Mn in groundwaters is 0.22–0.28 mg∙dm–3 and this concentration is not in accordance with the WHO. Chlorine is one of the most common disinfectants used in the water treatment industry because it has a low cost and immediate effect on the destruction of microorganisms, the concentration of chlorine (Cl2) in our research is 0.1–0.32 mg∙dm–3. The speed of chemical reactions in the technology of GW is extremely important because sometimes in the elimi-nation of chemical pollutants using oxidizing agents often form intermediate species. The speed of reactions indicates how fast chemical bonds are formed in the creation of a product, and this depends on the rate of reaction (XA). The focus for the research is to study the potassium permanganate and chlorine gas reactions in water if it forms intermediate products (in-termediate species) due to the high speed of reactions. Scientific research conclusion, intermediate species in the oxidation reactions of Mn and water disinfection with Cl2(g) it is impossible to cause a high rate of chemical reactions from the reac-tion rate (XA = 1%) to the reaction rate (XA = 99%). The maximum speed at the highest XA Cl2 is from 4.405∙10–11 to 8.87∙10–10 mol∙dm–3∙s–1, while at Mn is (2.030–4.034)∙10–7 mol∙dm–3∙s–1.
In this research different methods for measuring water quality indices were conducted to investigate the performance of the newly designed, constructed and operated 9-Nissan water treatment plant, Iraq. Data gathering and implementation took place throughout winter and summer. Water samples were taken periodically, according to the standard method, the re-search was carried out by collecting different random samples for eight months (Jun. 2015–Jan. 2016) and measuring (tur-bidity, total hardness, pH, total dissolved solids, suspended solids, Cl–, Mg2+, Fe2+,NO3–, NH3+) for each sample. Five dif-ferent approaches and methodologies of calculating the water index were applied. The results revealed that the Water Qual-ity Indices varied from 70.55 to 88.24, when applying Canadian Council of Ministers of the Environment Water Quality Index (CCMEWQI) and British Columbia water quality index (BCWQI) geometric weighted mean respectively. All the results, from the five approaches indicated good water quality, multiple regression analyses were conducted for turbidity, total hardness and suspended solids, they found that these parameters are strongly related to each other and to other pa-rameters.
The geographical location and climatic conditions of Ukraine cause the active development of land reclamation, as it enables to ensure stable and high yields. The complexity of forecasting in this area, namely the dependence of the results onthe changing weather and climate conditions, does not allow to effectively use the standard instruments for justifying the investment for agricultural and land reclamation innovation.
The necessity of improving methodological approaches to evaluating the effectiveness of investments in projects in the field of agricultural production and land reclamation was substantiated. The proposed approaches were tested on the ad-vanced technology of water treatment in irrigation based on using a vibrating gravitation filter enabling to perform simultaneously the processes of water treatment and filter element regeneration.
The obtained results clearly show that the advancedtechnology of irrigation water treatment and the developed for this technology design of the vibrating gravity filter are cost-effective. The current payback period for irrigation projects when using the purified water under this advanced technology is 5 years. It is the same as for the irrigation projects when using clean irrigation water.
Thus, our proposed approaches to the evaluation of investments in new water treatment technologies applied in irriga-tion enable to adapt the modern methodology of analysis of economic and investment efficiency of projects to the domestic needs of agricultural production, namely to take into account the impact of changing weather and climate conditions on the resulting economic parameters.
The Shatt Al Arab River (SAAR) is a major source of raw water for most water treatment plants (WTP’s) located along with it in Basrah province. This study aims to determine the effects of different variables on water quality of the SAAR, using multivariate statistical analysis. Seventeen variables were measured in nine WTP’s during 2017, these sites are Al Hussain (1), Awaissan (2), Al Abass (3), Al Garma (4), Mhaigran (5), Al Asmaee (6), Al Jubaila (7), Al Baradia (8), Al Lebani (9). The dataset is treated using principal component analysis (PCA) / factor analysis (FA), cluster analysis (CA) to the most important factors affecting water quality, sources of contamination and the suitability of water for drinking and irrigation. Three factors are responsible for the data structure representing 88.86% of the total variance in the dataset. CA shows three different groups of similarity between the sampling stations, in which station 5 (Mhaigran) is more contami-nated than others, while station 3 (Al Abass) and 6 (Al Asmaee) are less contaminated. Electrical conductivity (EC) and sodium adsorption ratio (SAR) are plotted on Richard diagram. It is shown that the samples of water of Mhaigran are locat-ed in the class of C4-S3 of very high salinity and sodium, water samples of Al Abass station, are located in the class of C3-S1 of high salinity and low sodium, and others are located in the class of C4-S2 of high salinity and medium sodium. Generally, the results of most water quality parameters reveal that SAAR is not within the permissible levels of drinking and irrigation.