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Abstract

This paper presents for the first time X-ray computed microtomography (μCT) analysis as a technique for Silurian graptolite detection in rocks. The samples come from the Jantar Bituminous Claystones Member of the Opalino core, Baltic Basin, northern Poland. Images were obtained with spatial resolution of 25 μm, which enabled the authors to create a 3-D visualization and to calculate the ratio of fissure and graptolite volume to the total sample volume. A set of μCT slices was used to create a 3-D reconstruction of graptolite geometry. These μCT slices were processed to obtain a clearly visible image and the volume ratio. A copper X-ray source filter was used during exposure to reduce radiograph artifacts. Visualization of graptolite tubaria (rhabdosomes) enabled Demirastrites simulans to be identified. Numerical models of graptolites reveal promising applications for paleontological research and thus for the recognition and characterization of reservoir rocks.
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Authors and Affiliations

Łukasz Kaczmarek
Anna Kozłowska
Michał Maksimczuk
Tomasz Wejrzanowski
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Abstract

The mid-Ludfordian pronounced, positive carbon isotope excursion (CIE), coincident with the Lau/kozlowskii extinction event, has been widely studied so far in shallow-water, carbonate successions, whereas its deep-water record remains insufficiently known. The aim of this research is to reconstruct the sedimentary environments and the palaeoredox conditions in the axial part of the Baltic-Podolian Basin during the event. For these purposes, the Pasłęk IG-1 core section has been examined using microfacies analysis, framboid pyrite diameter and carbon isotope measurements. The prelude to the event records an increased influx of detrital dolomite interpreted as eolian dust, coupled with a pronounced decrease in the diameter of the pyrite framboids, indicating persistent euxinic conditions across the event. The event climax is recorded as the Reda Member and consists of calcisiltites, composed of calcite microcrystals (‘sparoids’), which are interpreted as suspensoids induced by phytoplankton blooms in the hipersaturation conditions present in the epipelagic layer of the basin. Both the prelude and climax facies show lamination, interpreted as having resulted from periodical settling of marine snow, combined with hydraulic sorting within a ‘benthic flocculent layer’, which additionally may be responsible for a low organic matter preservation rate due to methanogenic decomposition. Contrary to the observed basinward CIE decline in the benthic carbonates in the basin, the Reda Member records an extremely positive CIE (up to 8.25‰). Given the pelagic origin of the sparoids, the CIE seems to record surface-water carbon isotope ratios. This points to a large carbon isotope gradient and kinetic fractionation between surface and bottom waters during the mid-Ludfordian event in a strongly stratified basin. The Reda facies-isotope anomaly is regarded as undoubtedly globally triggered, but amplified by the stratified and euxinic conditions in the partly isolated, Baltic-Podolian basin. Hence, the common interpretation of the basin record as representative for the global ocean needs to be treated with great caution.

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Authors and Affiliations

Wojciech Kozłowski

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