The work determined the influence of aluminium in the amount from about 1% to about 7% on the graphite precipitates in cast iron with
relatively high silicon content (3.4% to 3.90%) and low manganese content (about 0.1%). The cast iron was spheroidized with cerium
mixture and graphitized with ferrosilicon. The performed treatment resulted in occurring of compact graphite precipitates, mainly nodular
and vermicular, of various size. The following parameters were determined: the area percentage occupied by graphite, perimeters of
graphite precipitates per unit area, and the number of graphite precipitates per unit area. The examinations were performed by means of
computer image analyser, taking into account four classes of shape factor. It was found that as the aluminium content in cast iron increases
from about 1.1% to about 3.4%, the number of graphite precipitates rises from about 700 to about 1000 per square mm. For higher
Al content (4.2% to 6.8%) this number falls within the range of 1300 – 1500 precipitates/mm2
. The degree of cast iron spheroidization
increases with an increase in aluminium content within the examined range, though when Al content exceeds about 2.8%, the area
occupied by graphite decreases. The average size of graphite precipitates is equal to 11-15 μm in cast iron containing aluminium in the
quantity from about 1.1% to about 3.4%, and for higher Al content it decreases to about 6 μm.
The influence of aluminium (added in quantity from about 0.6% to about 2.8%) on both the alloy matrix and the shape of graphite precipitates in cast iron treated with a fixed amounts of cerium mischmetal (0.11%) and ferrosilicon (1.29%) is discussed in the paper. The metallographic examinations were carried out for specimens cut out of the separately cast rods of 20 mm diameter. It was found that the addition of aluminium in the amounts from about 0.6% to about 1.1% to the cast iron containing about 3% of carbon, about 3.7% of silicon (after graphitizing modification), and 0.1% of manganese leads to the occurrence of the ferrite-pearlite matrix containing cementite precipitates in the case of the treatment of the alloy with cerium mischmetal . The increase in the quantity of aluminium up to about 1.9% or up to about 2.8% results either in purely ferrite matrix in this first case or in ferrite matrix containing small amounts of pearlite in the latter one. Nodular graphite precipitates occurred only in cast iron containing 1.9% or 2.8% of aluminium, and the greater aluminium content resulted in the higher degree of graphite spheroidization. The noticeable amount of vermicular graphite precipitates accompanied the nodular graphite.
The influence of aluminium added in amounts of about 1.6%, 2.1%, or 2.8% on the effectiveness of cast iron spheroidization
with magnesium was determined. The cast iron was melted and treated with FeSiMg7 master alloy under industrial conditions.
The metallographic examinations were performed for the separately cast rods of 20 mm diameter. They included the assessment of the
shape of graphite precipitates and of the matrix structure. The results allowed to state that the despheroidizing influence of aluminium
(introduced in the above mentioned quantities) is the stronger, the higher is the aluminium content in the alloy. The results of examinations
carried out by means of a computer image analyser enabled the quantitative assessment of the considered aluminium addition influence.
It was found that the despheroidizing influence of aluminium (up to about 2.8%) yields the crystallization of either the deformed nodular
graphite precipitates or vermicular graphite precipitates. None of the examined specimens, however, contained the flake graphite
precipitates. The results of examinations confirmed the already known opinion that aluminium widens the range of ferrite crystallization.
The paper presents an analysis of a selected grade of high silicon cast iron intended for work in corrosive and abrasive conditions. The text describes its microstructure taking into account the process of crystallization, TDA analysis, EDS, XRD and the chemical composition analysis. In order to determine the phase composition, X-ray diffraction tests were carried out. The tests were executed on a Panalytical X'Pert PRO X-ray diffractometer with filtration of radiation from a lamp with copper anode and PIXcel 3D detector on the deflected beam axis. Completed tests allowed to describe the microstructure with detailed consideration of intermetallic phases present in the alloy. Results of the analysis of the examined alloy clearly show that we deal with intermetallic phases of Fe3Si, Fe5Si3 types, as well as silicon ferrite and crystals of silicon. In the examined alloy, we observed the phenomenon of segregation of carbon, which, as a result of this process, enriches the surface of silicon crystals, not creating a compound with it. Moreover, the paper demonstrates capability for crystallization of spheroidal graphite in the examined alloy despite lack of elements that contribute to balling in the charge materials.
This paper describes the possibility of using very short periods of solution annealing in the heat treatment of unmodified hypoeutectic silumin alloy AlSi7Mg0,3 casted by method of casting with crystallization under pressure with forced convection (direct squeeze casting process). Castings prepared at different casting parameters were subjected to special heat treatment called SST (Silicon Spheroidization Treatment), which were originally used only for the modified silumin alloys to spheroidization of eutectic silicon. Temperature holding time in solution annealing of T6 heat treatment is limited in the SST process to only a few minutes. It was studied the effect of casting parameters and periods of solution annealing on ultimate strength, yield strength, and especially ductility that in the unmodified silumin alloy castings is relatively low.
The effectiveness of cast iron spheroidization with FeSiMg master alloy by the traditional method and using a reaction chamber placed in the cavity of foundry mould was compared. The method of cast iron treatment in mould cavity using a reaction chamber is an innovative technology developed by the Foundry Research Institute in Krakow. The effectiveness of the spheroidization process carried out by both methods was checked on a series of test castings. The article also presents the results of metallographic examinations and mechanical testing, including the discussion of magnesium yield and its assimilation rate.
The work presents results of investigations concerning the production of cast iron containing about 5-6% aluminium, with the ferritic
matrix in the as-cast state and nodular or vermicular graphite precipitates. The examined cast iron came from six melts produced under the
laboratory conditions. It contained aluminium in the amount of 5.15% to 6.02% (carbon in the amount of 2.41% to 2.87%, silicon in the
amount of 4.50% to 5.30%, and manganese in the amount of 0.12% to 0.14%). After its treatment with cerium mixture and graphitization
with ferrosilicon (75% Si), only nodular and vermicular graphite precipitates were achieved in the examined cast iron. Moreover, it is
possible to achieve the alloy of pure ferritic matrix, even after the spheroidizing treatment, when both the aluminium and the silicon occur
in cast iron in amounts of about 5.2÷5.3%.