In this article the structural and mechanical properties of grain refinement of Cu-Sn alloys with tin content of 10%, 15% and 20% using the KOBO method have been presented. The direct extrusion by KOBO (name from the combination of the first two letters of the names of its inventors – A. Korbel and W. Bochniak) method employs, during the course of the whole process, a phenomenon of permanent change of strain travel, realized by a periodical, two-sided, plastic metal torsion. Moreover the aim of this work was to study corrosion resistance. The microstructure investigations were performed using an optical microscope Olimpus GX71, a scanning electron microscope (SEM) and a scanning transmission electron microscope (STEM). The mechanical properties were determined with INSTRON 4505/5500 machine. Corrosion tests were performed using «Autolab» set – potentiostat/galvanostat from EcoChemie B.V. with GPES software ver. 4.9. The obtained results showed possibility of KOBO deformation of Cu-Sn casting alloys. KOBO processing contributed to the refinement of grains and improved mechanical properties of the alloys. The addition of tin significantly improved the hardness. Meanwhile, with the increase of tin content the tensile strength and yield strength of alloys decrease gradually. Ductility is controlled by eutectoid composition and especially δ phase, because they initiate nucleation of void at the particle/matrix interface. No significant differences in the corrosion resistance between cast and KOBO processed materials were found.
High-tin bronzes are used for church bells and concert bells (carillons). Therefore, beside their decorative value, they should also offer
other functional properties, including their permanence and good quality of sound. The latter is highly influenced by the structure of bell
material, i.e. mostly by the presence of internal porosity which interferes with vibration of the bell waist and rim, and therefore should be
eliminated. The presented investigations concerning the influence of tin content ranging from 20 to 24 wt% on mechanical properties of
high-tin bronzes allowed to prove the increase in hardness of these alloys with simultaneous decrease in the tensile and the impact
strengths (Rm and KV, respectively) for the increased tin content. Fractures of examined specimens, their porosity and microstructures
were also assessed to explain the observed regularities. A reason of the change in the values of mechanical properties was revealed to be
the change in the shape of α-phase crystals from dendritic to acicular one, and generation of grain structure related to the increased Sn
content in the alloy.
The most important feature of bells is their sound. Their clarity and beauty depend, first of all, on the bell’s geometry - particularly the shape of its profile and the mechanical properties of alloy. Bells are the castings that work by emitting sound in as-cast state. Therefore all features that are created during melting, pouring, solidification and cooling processes will influence the bell's sound. The mechanical properties of bronze depend on the quality of alloy and microstructure which is created during solidification and depend on its kinetics. Hence, if the solidification parameters influence the alloy’s properties, how could they influence the frequencies of bell`s tone? Taking into account alterable thickness of bell's wall and differences in microstructure, the alloy's properties in bell could be important. In the article authors present the investigations conducted to determine the influence of cooling kinetics on microstructure of bronze with 20 weight % tin contents.
The most important feature of bells is their sound. Its clarity and beauty depend, first of all, on the bell’s geometry - particularly the shape
of its profile, but also on the quality of alloy used to its cast. Hence, if the melting and pouring parameters could influence the alloy’s
properties, what influence they would have on the frequencies of bell’s tone. In the article authors present their own approaches to find
answers on that and more questions.
The mold temperature of the downward continuous unidirectional solidification (CUS) cannot be controlled higher than the liquidus of alloys to be cast. Therefore, the continuous casting speed becomes the main parameter for controlling the growth of columnar crystal structure of the alloy. In this paper, the tin bronze alloy was prepared by the downward CUS process. The microstructure evolution of the CUS tin bronze alloy at different continuous casting speeds was analysed. In order to further explain the columnar crystal evolution, a relation between the growth rate of columnar crystal and the continuous casting speed during the CUS process was built. The results show that the CUS tin bronze alloy mainly consists of columnar crystals and equiaxed crystals when the casting speed is low. As the continuous casting speed increases, the equiaxed crystals begin to disappear. The diameter of the columnar crystal increases with the continuous casting speed increasing and the number of columnar crystal decreases. The growth rate of columnar crystal increases with increasing of the continuous casting speed during CUS tin bronze alloy process.