Sorghum produces allelopathic compounds, including total phenolic compounds and sorgoleone, which exhibit a phytotoxic effect on weeds. The field study, carried out in 2016-2017, was designed as an one-factor experiment, in the randomized block design, in four replications, with Sucrosorgo 506, Rona 1, KWS Freya, KWS Juno, and KWS Sammos, to assess the impact of allelochemicals on weeds. Weed infestation was determined at the beginning of July. Individual weed species were collected from two random places in each plot and weighed. The aim of the laboratory study was to evaluate the total content of phenolic compounds, and sorgoleone in the early stages of plant development (5, 10, and 15 days after emergence) in varieties Rona 1, KWS Freya, KWS Juno, KWS Sammos, Farmsorgo 180, GK Aron, PR 845F, Sucrosorgo 506 and PR849F. The total content of phenolic compounds was determined using the colorimetric method, and the sorgoleone HPLC technique on a Flexar chromatographic set. The highest value of sorgoleone was observed in 15-day-old seedlings of KWS Juno, the lowest in 5-day-old seedlings of Sucrosorgo 506, the highest levels of total phenolic compounds in 5-day-old seedlings of PR 845F, the lowest in 15-day-old seedlings of Farmsorgo 180. The results do not fully confirm the beneficial effect of allelopathic compounds on reducing weed infestation, however, it is important to emphasize the diversity of cultivars used. The statistically insignificant results indicated that most varieties of sorghum plants do not exhibit a significant decrease in yield.

Recent studies in the area of biological air treatment in filters have addressed fundamental key issues, such as a biofilter bed of different origin composed of natural zeolite granules, foam cubes and wood chips. When foam and zeolite are mixed with wood chips to remove volatile organic compounds from the air, not only biological but also adsorption air purification methods are accomplished. The use of complex purification technologies helps to improve the efficiency of a filter as well as the bed service life of the filter bed. Investigations revealed that microorganisms prevailing in biological purification, can also reproduce themselves in biofilter beds of inorganic and synthetic origin composed of natural zeolite and foam. By cultivating associations of spontaneous microorganisms in the filter bed the dependencies of the purification efficiency of filter on the origin, concentration and filtration time of injected pollutants were determined. The highest purification efficiency was obtained when air polluted with acetone vapour was supplied to the equipment at 0.1 m/s of superficial gas velocity. When cleaning air from volatile organic compounds (acetone, toluene and butanol), under the initial pollutant concentration of ~100 mg/m3, the filter efficiency reached 95 %.

Endocrine disrupting compounds (EDCs) have the potential to alter hormone pathways that regulate life processes in humans, vertebrates and invertebrates. Besides xcnobiotics having endocrine effects, there arc naturally occurring estrogenie compounds. The limited number of studies with EDCs in invertebrates is partially due to the fact that their hormonal systems are rather poorly understood in comparison with vertebrates. It is also important, but difficult to discriminate between hormone - mediated and other toxicological modes of action. Data of the potentially adverse impact of EDCs on wildlife species are reviewed.

The energy industry is undergoing a major upheaval. In Germany, for example, the large nuclear and coal-fired power plants in the gigawatt scale are planned to be shut down in the forthcoming years. Electricity is to be generated in many small units in a decentralized, renewable and environmentally friendly manner. The large 1000 MW multistage axial steam turbines used to this date are no longer suitable for these tasks. For this reason, the authors examine turbine architectures that are known per se but have fallen into oblivion due to their inferior efficiency and upcoming electric drives about 100 year ago. However, these uncommon turbine concepts could be suitable for small to micro scale distributed power plants using thermodynamic cycles, which use for example geothermal wells or waste heat from industry to generate electricity close to the consumers. Thus, the paper describes and discusses the concept of a velocity-compounded single wheel re-entry cantilever turbine in comparison with other turbine concepts, especially other velocity-compounded turbines like the Curtis-type. Furthermore, the authors describe the design considerations, which led to a specific design of a 5 kW air turbine demonstrator, which was later manufactured and investigated. Finally, first numerical as well as experimental results are presented, compared and critically discussed with regards to the originally defined design approach.

The objective of the study was to compare the impact of three systems of multiannual fertilization applied in two long-term field experiments on the content of phenolic compounds in the soil. In the study, both natural (manure, slurry) and mineral (NPK) fertilizers were used, along with combined, organic-and-mineral fertilization. Experiment I was established in 1972 on grey brown podzolic soil; experiment II, in 1973 on brown soil. In both experiments crops were cultivated in a 7-year rotation, with a 75% share of cereals. The experimental samples were taken from the top layer of soil after 36 (experiment I) and 35 (experiment II) years following the establishment of the experiments. It was demonstrated that the presence of phenolic compounds in the soils was significantly dependent on the contents of organic C and total N, type of soil and the type and dose of used fertilizers. In grey brown podzolic soil, the content of total phenolic compounds was at a lower level than the content found in brown soil. Multiannual fertilization contributed to an increase in the content of total phenolic compounds in relation to the values obtained in control objects, which was particularly reflected in the soil originating from objects fertilized with slurry applied at a dose being equivalent to manure in terms of the amount of introduced organic carbon. The percentage of water-soluble phenols in the total content of these compounds in grey brown podzolic soil was at the level of 18.4%, while in brown soil it amounted to 29.1%.

Allelopathy is a complex phenomenon which depends on allelochemical concentrations. So, two pot experiments were carried out to investigate the allelopathic effect of alcoholic fresh shoot extract of Eruca sativa (foliar spray) and E. sativa shoot powder (mixed with soil) on Pisum sativum plants and two associated weeds, Phalaris minor and Beta vulgaris. The experiments were conducted in the greenhouse of the National Research Centre, Giza, Egypt during two successive winter seasons (2016–2017 and 2017–2018). Ten treatments were applied in this study. Four treatments were applied before sowing, that E. sativa shoot powder was mixed with the soil at rates of 15, 30, 45 and 60 g ⋅ pot–1. The other four treatments of E. sativa alcoholic fresh shoot extract were sprayed twice on both plants and weeds at 5, 10, 15 and 20% (w/v) concentrations. Additionally, two untreated treatments, healthy (P. sativum only) and unweeded (untreated infested P. sativum plants with weeds) were applied for comparison. The results indicated that both alcoholic extracts and powder reduced growth of both weeds. Moreover, there was a direct relationship between concentration and weed reduction. Eruca sativa alcoholic extracts increased yield parameters of P. sativum plants. The maximum yield attributes were recorded by spraying of E. sativa alcoholic extract at 20%. On the other hand, it was clearly noticed that the high powder rates affected negatively P. sativum yield parameters. But the lowest powder rate (15 g ⋅ pot–1) stimulated P. sativum yield parameters as compared to unweeded treatment. Chemical analysis of E. sativa shoot powder ensured that the abundant amount of glucosinolates (9.6 μmol ⋅ g–1) and phenolic compounds (46.5 mg ⋅ g–1) may be responsible for its allelopathic effect. In conclusion, spraying of alcoholic fresh shoot extract of E. sativa at 20% (w/v) and mixing E. sativa shoot powder at 15 g · pot–1can be applied as natural bioherbicides for controlling weeds.

The paper presents investigation results of the migration of a chemical compound contained in fly ash deposited on a dry furnace waste landfill site exposed to weather conditions. Climate conditions are able to significantly affect chemical component distribution in a block of deposited, moving chemical compounds to different depths. The main aim of the investigations was to determine the chemical component distribution of deposited fly ash in the landfill. Identification of chemical components based on XRF analysis indicated the existence of differences in both tested storage layer and the fraction of fly ash.

The gas porosity is one of the most serious problems in the casting of aluminum. There are several degassing methods that have been

studied. During smelting of aluminum, the intermetallic compound (IMC) may be formed at the interface between molten aluminum and

solid steel of crucible furnace lining. In this study, the effect of degassing treatment on the formations of IMC has been investigated. The

rectangular substrate specimens were immersed in a molten aluminum bath. The holding times of the substrate immersions were in the

range from 300 s to 1500 s. Two degassing treatments, argon degassing and hexachloroethane tablet degassing, were conducted to

investigate their effect on the IMC formation. The IMC was examined under scanning electron microscope with EDX attachment. The

thickness of the IMC layer increased with increasing immersion time for all treatments. Due to the high content of hydrogen, substrate

specimens immersed in molten aluminum without degasser had IMC layer which was thicker than others. Argon degassing treatment was

more effective than tablet degassing to reduce the IMC growth. Furthermore, the hard and brittle phase of IMC, FeAl3, was formed

dominantly in specimens immersed for 900 s without degasser while in argon and tablet degasser specimens, it was formed partially.

In the morphosyntactic literature, there exist two approaches to the problem of argument structure in English nominal synthetic compounds such as furniture moving or dog training. According to Borer (2012), such synthetic compounds belong to the class of referential nominals and thus lack argument structure. On the other hand, Alexiadou (2017) maintains that the external argument is present in the structure of synthetic compounds due to their ability to co-occur with by-phrases. In this paper, we present an extensive set of corpus data to show that synthetic -ing compounds do project the external argument, which is evidenced by their ability to license not only by-phrases but also agent-oriented adjectives and instrumental phrases. Importantly, the corpus data indicates that certain synthetic -ing compounds display the capacity to occur in aspectual contexts; nominal compounds fall in two classes in that regard.

During the process of ,,enhanced coagulation" except for colloids and suspensions removal, the removal of associated organic compounds including DPD (Disinfection By-Products) precursors is crucial. It is often necessary to decrease color and turbidity of treated water to values which arc significantly lower than accepted for drinking water. On the basis of presented results of the research it was found out that under strict technological conditions coagulation of low mineralization waters ensures effective treatment, including significant THMs precursors removal, even when water is of low temperature. However, it is necessary to apply two different methods of coagulation (volumetric coagulation and direct filtration) dependently of water temperature with the usage of the same equipment (a flocculation chamber, a vertical sedimentation tank and a pressure rapid filter) including the same point of a coagulant dosing. During the periods of ,,high temperature" the treatment should be based on volumetric coagulation and during the periods of ,,low temperature" of water direct filtration should be applied.

In this work the effectiveness of the biotransformation of phosphogypsum in the cultures of sulphatereducing bacteria (SRB) was studied. SRB were isolated from soil contaminated with automobile fuel. The microorganisms were grown by two methods: the enrichment of the cultures and microcosms in: Postgate, minimal medium (with phenol, acetate or lactate) and Emerson medium. All media contained phosphogypsum as electron acceptors. The isolated microorganisms were passage in medium containing different carbon compounds: ethanol, lactate, phenol, acetate casein or lactose to test the effectiveness of biotransformation of phosphogypsum depending on the source of carbon used. In cultures in Postgate medium with lactate or casein there were found the maximal H2S concentration (654 and 540 mg HS-/dm3) and maximal decrease of phosphogypsum 84% and 64%, respectively. The isolated microorganisms utilised alcohol, sugar, protein and phenol.

The landfill gas (LFG), produced during decomposition of the organic fraction of waste is a major source of air pollutants. It consists mainly of methane and carbon dioxide, but also contains additional gases, such as nitrogen, oxygen, hydrogen, carbon monoxide, hydrogen sulphide, and a large number of trace components. Aliphatic and aromatic hydrocarbons, halogenated hydrocarbons, heterocyclic compounds, alcohols, aldehydes, ketones, terpenes and siloxanes belong to this group. This work presents the results of field studies concerning the concentration of over fifty non-methane organic compounds in municipal solid waste landfill gas. The sites examined were located in the Middle East macroregion of Poland. The landfills were different in the respect to size, morphology, and age of stored waste. The results reveal that the highest concentrations of the majority of the examined compounds were observed in gas released from the largest landfill at which the waste was not pre-treated prior to deposition. Concentrations often exceeded those found in the literature data. Deposition of waste after separation of biofraction and recyclable materials significantly decreased concentrations of the majority of NMOCs in the LFG.

The market value of essential oils is steadily increasing every year. They are mainly used as aromas and preservatives in food and cosmetics industries. The content and yield of the obtained extracts change across the seasons of the year. The knowledge of these differences is important for essential oils industry to gain the best quality and quantity of products. In this study Thuja occidentalis L. (Eng. northern white cedar) extract was obtained from leaves by maceration in dichloromethane. Plant material was collected during each season of the year and the finished products were thoroughly examined through GC-MS analysis. The seasonal variations of volatile compound composition showed that the most adequate period to obtain T. occidentalis extract on an industrial scale is spring. This is due to the best efficiency (almost 10%) and the highest content of monoterpenes (67%).

The subject of this review is the monograph of Marta Vojteková on the new compounds with initial baseoids of foreign origin in contemporary Polish.
The author describes Polish lexicon occurring in the Polish press in 2001–2005 excerpted from the work by Teresa Smółkowa (ed.), Nowe słownictwo polskie. Materiały z prasy lat 2001–2005. Vojteková presents the set of 276 baseoids occurring as the initial part of compounds gathered as a dictionary, which can serve as a starting point for the preparation new neological sources or for further linguistic research on baseoids.

Research on the chemistry of atmospheric precipitation in the Hornsund region of Svalbard has been extended by analysis of the organic contents. In rainfall samples collected in September 2003, the organics were separated by solid phase extraction (SPE), eluted and analysed on gas chromatograph coupled to a mass selective detector (GC/MS). Rainfall pH was in the range 4.72–5.45, the low values suggesting possible pollution. Concentrations of inorganic ions, expressed as total dissolved salts (TDS), were 5.40–13.18 mg L–1. Non-sea-salt (nss) sulphates were in the range 5–11 μeq L–1. In all samples, long-chain alkanes with chain length up to C36, and their methyl derivatives were detected. Among aromatic compounds biphenyl, dibenzofuran and its methyl derivatives were found. Polycyclic aromatic hydrocarbons (PAHs) were represented by naphthalene, phenanthrene, fluorene, acenaphthene, fluoranthene and pyrene. There were no PAHs with higher numbers of rings. The synoptic meteorological conditions in September 2003 indicate that all organic and inorganic pollutants were of local origin.

The leaves of wheat infected by powdery mildew Erisiphe graminis var. tritici manifested repellent action against cereal aphids Rhopalosiphum padi and Sitobion avenae. Food (leaves) for aphids enriched in chemical components present in diseased leaves caused weaker reproduction of S. avenae and mortal i ty of R. pad i. It could be caused by post-infection increase of the level of monophenols and flavanoids in the leaves of wheat infected by powdery mildew (E. graminis var. tritici). These compounds increasing IAA-oxidase activity in plants can have a harmful influence on the cereal aphids.

In this paper, of primary interest is to synthesis 8-(1H-indol-3-ylazo)-naphthalene-2-sulfonic acid (INSA) and to evaluate the main parameters of Au/INSA/n-Si/Al diode in dark and under illumination. Different techniques are used for interpreting the proposed INSA chemical structure. The dark current-voltage measurements were achieved in the temperature range of 293−413 K. It is noticed that INSA films modify the interfacial barrier height of classical Au/n-Si junction. At low applied voltages, the I–V relation shows exponential behavior. The values ideality factor, n, and the barrier height, φ, are improved by heating. The abnormal trend of n and φ is discussed, and a homogenous barrier height of 1.45 eV is evaluated. The series resistance is also calculated using Norde's function and it changes inversely with temperature. The space charge limited current ruled with exponential trap distribution dominates at relatively high potentials, trap concentration and carriers mobility are extracted. The reverse current of the diode has illumination intensity dependence with a good photosensitivity indicating that the device is promising for photodiode applications.

The research was conducted to evaluate the impact of sulphur compounds on the sex of Colorado potato beetle in the region of sulphur factory in Chmielów near Tarnobrzeg in 1995. The control plantations were situated in the village of Zarębki, about 30km from Chmielów. The object of the study was the average body mass of female and male specimen of the insect after full spring beetle appearance in potato plantations as well as the average body female and male mass after pupation of the larvae of the first generation and emerging from the soil. After six and twelve days of starvation, the average female and male body mass was determined. After twelve days of starvation the incident of cannibalism was noticed among the beetles of the first zone polluted by sulphur compounds.

Cultivation-based assays represent the gold standard for the assessment of virus infectivity; however, they are time-consuming and not suitable for every virus type. Pre-treatment with platinum (Pt) compounds followed by real-time PCR has been shown to discriminate between infectious and non-infectious RNA viruses. This study examined the effect of Pt and palladium (Pd) compounds on enveloped DNA viruses, paying attention to two significant pathogens of livestock – bovine herpesvirus-1 (BoHV-1) and African swine fever virus (ASFV). Native or heat-treated BoHV-1 suspension was incubated with the spectrum of Pt/Pd compounds. Bis(benzonitrile)palladium(II) dichloride (BB-PdCl ₂) and dichloro(1,5-cyclooctadiene) palladium(II) (PdCl ₂-COD) produced the highest differences found between native and heat- -treated viruses. Optimized pre-treatment conditions (1 mM of Pd compound, 15 min, 4°C) were applied on both virus genera and the heat inactivation profiles were assessed. A significant decrease in the detected quantity of BoHV-1 DNA and ASFV DNA after heat-treatment (60°C and 95°C) and consequent incubation with Pd compounds was observed. BB-PdCl ₂ and PdCl ₂-COD could help to distinguish between infectious and non-infectious enveloped DNA viruses such as BoHV-1 or ASFV.

A laboratory study was performed to study the effects of various operating factors, viz. adsorbent dose, contact time, solution pH, stirring speed, initial concentration and temperature on the adsorption of triphenyltin chloride (TPT) onto coal fly ash supported nZnO (CFAZ). The adsorption capacity increases with increase in the adsorbent amount, contact time, pH, stirring speed and initial TPT concentration, and decrease with increase in the solution temperature. The adsorption data have been analyzed by Langmuir, Freundlich, Temkin and Dubinin-Radushkevich (D-R) adsorption models to determine the mechanistic parameters associated with the adsorption process while the kinetic data were analyzed by pseudo first-order, pseudo second-order, Elovich, fractional power and intraparticle diffusivity kinetic models. The thermodynamic parameters of the process were also determined. The results of this study show that 0.5 g of CFAZ was able to remove up to 99.60% of TPT from contaminated natural seawater at 60 min contact time, stirring speed of 200 rpm and at a pH of 8. It was also found that the equilibrium and kinetic data fitted better to Freundlich and pseudo second-order models, respectively. It can therefore be concluded that CFAZ can be effectively used for shipyard process wastewater treatment

The aim of this study was to determine the impact of the temperature of wastewater in a biological reactor with activated sludge and the BOD₅/N-NH₄ ratio in the influent to the treatment plant on nitrification efficiency and the concentration of ammonium nitrogen in treated wastewater. Tests were carried out in a household wastewater treatment plant which collects and treats sewage from a school building and a teacher’s house. During the 3-year study, large fluctuations in the sewage temperature in bioreactor were noted which was closely related to the ambient temperature. There were also large fluctuations in the concentration of organic matter and the concentration of ammonium nitrogen in inflowing sewage. The influence of wastewater temperature in the bioreactor and the BOD₅/N-NH₄ ratio on the concentration of ammonium nitrogen in treated wastewater was determined using Pearson’s linear correlation. A statistical analysis showed that a 1°C decrease in the temperature of wastewater in the bioreactor increased the concentration of ammonium nitrogen in treated wastewater by 2.64 mgN-NH₄·L^-1. Moreover, it was found that nitrification depended on the ratio of BOD₅ to the concentration of ammonium nitrogen in wastewater flowing into the bioreactor. An increase in the BOD₅/N-NH₄ ratio by 1 value led to a 5.41 mgN-NH₄·L^-1 decrease in the concentration of ammonium nitrogen.

In the present study, the novel quaternary ammonium salt (QAS⁺), 1-methyl-di-octyl-1 phenyl ammonium iodide (QAS₁), was synthesized by complete alkylation reaction. Sodium montmorillonite (Mt) was modified via an ion-exchange reaction with QAS₁⁺. The modified material and quarternary ammonium salt (Mt₁ and QAS₁) were analyzed by nuclear magnetic resonance (NMR), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and scanning electron microscopy (SEM). Removal capacity of hydrophobic organic pollutants such as 4-nitrophenol (4-NP) and 2,4-dinitrophenol (2,4-DNP) from solution media of synthesized organoclay was evaluated. The optimum conditions and batch kinetics of adsorption of 4-nitrophenol and 2,4-dinitrophenol from aqueous solutions are reported. It was shown that the adsorption capacity decreased in the order 4-NP> 2,4-DNP. The total mass loss during the drying process was 66% and 78%, respectively. Thermodynamic parameters enthalpy (∆H⁰) and entropy (∆S⁰) and the mean free energy (E) for the adsorption of nitrophenol compounds (NCP) were determined.