This paper presents a method for quantitative assessment of the mechanisms of nucleation and granules growth by layering in the process of bed wetting during periodic disc granulation. This study included two initial, consecutive stages of a process with defined time courses. The first phase was a time period, in which only formation of new nuclei took place, while in the second stage simultaneous nucleation and growth of granules as a result of sticking raw material grains to pre-existing nuclei occurred. Different kinds of binding liquid were used for bed wetting in each phase. In the first phase, an aqueous solution of dye was used, and pure distilled water in the second stage. The contribution of particular mechanisms to the formation of agglomerates at different time points within the second phase of the process was determined in this study. To do that the results of bed granulometric analysis, mass balance of size fractions and the analysis of contents of a marker (dye) delivered to the bed with the binding liquid during the first phase in agglomerates were used. To assess the concentration of the dye in different size fractions of the batch, spectrophotometric analysis was utilised. The study was performed using UV-VIS JASCO V-630 spectrophotometer equipped with an integrating sphere. The sieve analysis, spectrophotometric studies and mass balance were used to determine changes in the weight of the dye containing nuclei and of the nuclei containing no dye. The aforementioned analyses were also used to assess changes in the weight of formed granules and of raw material particles attached to nuclei during simultaneous nucleation and growth of granules.

Analysis of granulation kinetics was carried out using a laboratory disc granulator with a diameter D of 0.5 m. A liquid binder was delivered to the tumbling bed at a constant flow rate with a nozzle generating droplets with a size of approx. 4-5 mm. Fine-grained chalk was used as a model of raw material and water or disaccharide solution with concentrations of 20 - 40% as a wetting liquid. Different times of droplet delivery ranging from 2 to 6 min were utilized. Granulometric composition of the bed for selected lengths of process, bed moisture and the moisture of individual size-fractions were assessed. Mass of granulated material, which was transferred from nuclei fraction to other size fractions was determined on the basis of mass balance analysis and the assessment of liquid migration between fractions. The influence of disaccharide concentration in wetting liquid on the aforementioned phenomena was also examined.

This paper presents the results of experimental drum granulation of silica flour with the use of wetting liquids with different values of surface tension. Additionally, different liquid jet breakup and different residual moisture of the bed were applied in the tests. The process was conducted periodically in two stages: wetting and proper granulation, during which no liquid was supplied to the bed. The condition of the granulated material after the period of wetting (particle size distribution and moisture of separate fractions) and a change in the particle size distribution during the further conduct of the process (granulation kinetics) were determined.

Deposits used as fertilizer bring to soil both biogens necessary for plant growth and other ingredients such as metals. including heavy metals. Knowledge of quantities and rate in which heavy metals are to be released to soil from granulates is important because of their toxic influence on plants (in the case of high metals concentration). This paper presents results of investigation of elution of Cu. Zn, Ni, Cd, Pb. and Cr from granulates prepared from municipal sewage sludge, hard coal ash and brown coal ash. Elution to water solution was carried out in static conditions with single-stage and tree-stage extraction. Heavy metal a component of sludge-ash granulates eluted in various quantities, i.e. from trace for cadmium to 9.26-9.53 mg/kg of d.m. for zinc. Among the soluble forms of metals the most mobile are (in decreasing sequence): Cu > Pb> Zn> Ni in granulates containing brown coal ash and Cu> Pb> Ni> Zn in granulates contain hard coal ash.

The results of investigations of the granulation process of foundry dusts generated in the dry mechanical reclamation process of used sands, where furan resins were binders are presented in the paper. Investigations concerned producing of granules of the determined dimensions and strength parameters. Granules were formed from the dusts mixture consisting in 50 mass% of dusts obtained after the reclamation of the furane sands and in 50 mass % of dusts from sands with bentonite. Dusts from the bentonite sands with water were used as a binder allowing the granulation of after reclamation dusts from the furane sands. The following parameters of the ready final product were determined: moisture content (W), shatter test of granules (Wz) performed directly after the granulation process and after 1, 3, 5, 10 days and nights of seasoning, water-resistance of granules after 24 hours of being immersed in water, surface porosity ep and volumetric porosity ev. In addition the shatter test and water-resistance of granulate dried at a temperature of 105oC were determined. Investigations were performed at the bowl angle of inclination 45o, for three rotational speeds of the bowl being: 10, 15, 20 rpm. For the speed of 10 rpm the granulation tests of dusts mixture after the preliminary mixing in the roller mixer and with the addition of water-glass in the amount of 2% in relation to the amount of dust were carried out. The obtained results indicate that the granulator allows to obtain granules from dusts originated from the reclamations of moulding sands with the furane resin with an addition of dusts from the bentonite sands processing plants.

The application of fluidized fly ash in underground mining excavations is limited due to its significant content of free calcium and calcium sulfate. In order to increase the amount of utilized fly ash from fluidized beds, it should be converted to a product with properties that meet the requirements for mining applications. This research presents the results of an attempt to adapt fluidized fly ashes for use in underground mining techniques, by means of carbonation and granulation. Carbonation was performed with the use of technical carbon dioxide and resulted in the reduction of free calcium content to a value below 1%. Granulation on the other hand, resulted in obtaining a product with good physical and mechanical parameters. The performed mineralogical and chemical studies indicate that trace amounts of “binding” phases, such as basanite and/or gypsum are present in the carbonized ash. The addition of water, during the granulation of carbonized fluidized fly ash, resulted in changes in the mineral phases leading to the formation of ettringite and gypsum as well as the recrystallization of the amorphous substance. It was confirmed that the carbonization and granulation of flying fluidized ashes positively affects the possibility of using these ashes in underground mining excavations.

This paper elucidated the potential of electron backscatter diffraction analysis for ground granulated blast furnace slag geopolymers at 1000°C heating temperature. The specimen was prepared through the mechanical ground with sandpaper and diamond pad before polished with diamond suspension. By using advanced technique electron backscatter diffraction, the microstructure analysis and elemental distribution were mapped. The details on the crystalline minerals, including gehlenite, mayenite, tobermorite and calcite were easily traced. Moreover, the experimental Kikuchi diffraction patterns were utilized to generate a self-consistent reference for the electron backscatter diffraction pattern matching. From the electron backscatter diffraction, the locally varying crystal orientation in slag geopolymers sample of monoclinic crystal observed in hedenbergite, orthorhombic crystal in tobermorite and hexagonal crystal in calcite at 1000°C heating temperature.

With the increase in wall thickness of the casting of iron-nickel-aluminium-bronze, by the reduction of the cooling rate the size of κII phase

precipitates increases. This process, in the case of complex aluminium bronzes with additions of Cr, Mo and W is increased. Crystallization

of big κII phase, during slow cooling of the casting, reduces the concentration of additives introduced to the bronze matrix and hardness.

Undertaken research to develop technology of thick-walled products (g> 6 mm) of complex aluminium bronzes. Particular attention

was paid to the metallurgy of granules. As a result, a large cooling speed of the alloy, and also high-speed solidification casting a light

weight of the granules allows: to avoid micro-and macrosegregation, decreasing the particle size, increase the dispersion of phases in

multiphase alloys. Depending on the size granules as possible is to provide finished products with a wall thickness greater than 6 mm by

infiltration of liquid alloy of granules (composites). Preliminary studies was conducted using drip method granulate of CuAl10Fe5Ni5

bronze melted in a INDUTHERM-VC 500 D Vacuum Pressure Casting Machine. This bronze is a starting alloy for the preparation of the

complex aluminium bronzes with additions of Cr, Mo, W and C or Si. Optimizations of granulation process was carried out. As the process

control parameters taken a casting temperature t (°C) and the path h (mm) of free-fall of the metal droplets in the surrounding atmosphere

before it is intensively cooled in a container of water. The granulate was subjected to a sieve analysis. For the objective function was

assume maximize of the product of Um*n, the percentage weight "Um" and the quantity of granules 'n' in the mesh fraction. The maximum

value of the ratio obtained for mesh fraction a sieve with a mesh aperture of 6.3 mm. In the intensively cooled granule of bronze was

identified microstructure composed of phases: β and fine bainite (α+β'+β'1) and a small quantity of small precipitates κII phase. Get high

microhardness bronze at the level of 323±27,9 HV0,1.

Significant quantities of coal sludge are created during the coal enrichment processes in the mechanical processing plants of hard coal mines (waste group 01). These are the smallest grain classes with a grain size below 1 mm, in which the classes below 0.035 mm constitute up to 60% of their composition and the heat of combustion is at the level of 10 MJ/kg. The high moisture of coal sludge is characteristic, which after dewatering on filter presses reaches the value of 16–28% (Wtot r) (archival paper PG SILESIA). The fine-grained nature and high moisture of the material cause great difficulties at the stage of transport, loading and unloading of the material. The paper presents the results of pelletizing (granulating) grinding of coal sludge by itself and the piling of coal sludge with additional material, which is to improve the sludge energy properties. The piling process itself is primarily intended to improve transport possibilities. Initial tests have been undertaken to show changes in parameters by preparing coal sludge mixtures (PG SILESIA) with lignite coal dusts (LEAG). The process of piling sludge and their mixtures on an AGH laboratory vibratory grinder construction was carried out. As a result of the tests, it can be concluded that all mixtures are susceptible to granulation. This process undoubtedly broadens the transport possibilities of the material. The grain composition of the obtained material after granulation is satisfactory. Up to 2 to 20 mm granules make up 90–95% of the product weight. The strength of the fresh pellets is satisfactory and comparable for all mixtures. Fresh lumps subjected to a test for discharges from a height of 700 mm can withstand from 7 to 14 discharges. The strength of the pellets after longer seasoning, from the height of 500 mm, shows different values for the analyzed samples. The values obtained for hard coal sludge and their blends with brown coal dust are at the level from 4 to 5 discharges. The strength obtained is sufficient to determine the possibility of their transport. At this stage of the work it can be stated that the addition of coal dust from lignite does not cause the deterioration of the material’s strength with respect to clean coal sludge. Therefore, there is no negative impact on the transportability of the granulated material. As a result of mixing with coal dusts, it is possible to increase their energy value (Klojzy-Karczmarczyk at al. 2018). The cost analysis of the analyzed project was not carried out.

Hard coal sludge is classified as group 01 waste or it is a by-product in the production of a hard coal with variable energy importance. Pulverized lignite is not waste but a final product of drying and the very fine pulverization of lignite with a high calorific value. The study comprised the basic material before granulation such as coal sludge (PG SILESIA) and pulverized lignite (LEAG) as well as their prepared blends after the granulation on a pipe vibration granulator designed at AGH. The pulverized lignite of the LEAG company shows a low sulfur contents. In the analyzed samples its average content (Stot d) is 0.61%. An average value of this parameter in the analyzed coal sludge samples is 0.55%. The addition of pulverized lignite does not have a significant impact on the total content of sulfur and of analyzed toxic elements (Hg, As, Cd, Cr, Co, Cu, Mn, Ni, Pb, Sb, Tl, and W) in the samples. The calorific value of coal sludge falls within the range of 11.0−12.4 MJ/kg (on a dry basis). For the coal sludge and pulverized lignite blends the calorific value clearly increases to values of 14.8−17.7 MJ/kg (on dry basis). The calorific value slightly decreases in the

The article analyzes the influence of selected factors on the activity rate of cement binder containing 50% of ground granulated blast furnace slag in its composition. These factors are the chemical and mineral composition of Portland cement CEM I, the degree of grinding of granulated blast furnace slag and Portland cement, and the water/binder ratio. This slag content is characteristic for blast furnace cement CEM III/A. In addition to the application effects, this type of cement is a low-carbon binder (there is a reduction of CO ₂ emissions by about 45% compared to Portland cement CEM I). The use of this type of cement in the composition of concrete enables the obtaining of concrete with a very small carbon footprint. Based on the results of our own research, it was found that such a high proportion of ground granulated blast furnace slag in the binder composition leads to a significant reduction in the early compressive strength of standard mortars (after two and seven days of setting). This results in a significant reduction in the use of these types of binders (cements) in selected areas of construction, e.g. prefabrication and high-strength concrete. Analyzing the obtained results of their own research, the authors concluded that the early strength of these types of binders can be significantly improved by increasing the specific surface area (degree of grinding) of Portland cement CEM I and lowering the water/slag ratio (w/s, where: s = cement + slag). The proposed material and technological modifications also enable the obtaining of higher compressive strength at all tested dates. The strength of the standard (after twenty-eight days and over longer periods) is comparable to or higher than that of Portland cement CEM I.

The effects of supplementary cementitious materials (SCM) on the characteristics and internal structure of synthetic aggregate made from ground granulated blast furnace slag are investigated in this study (GGBS). Due to its high pozzolanic activity, GGBS was shown to be superior to other SCM materials, enhancing both the strength and durability of synthetic aggregate. Because sintering uses a lot of energy and generates a lot of pollutants, using a cold-bonded approach to make low density lightweight aggregates is particularly significant from an economic and environmental standpoint. Thus, the utilisation of ground granulated blast furnace slag (GGBS) as a substitute material in the production of green artificial lightweight aggregate (GLA) using the cold bonding method was discussed in this work. Admixtures of ADVA Cast 203 and Hydrogen Peroxide were utilised to improve the quality of GLA at various molar ratios. The freshly extracted GLA was then evaluated for specific gravity, water absorption, aggregate impact, and aggregate crushing in order to determine the optimal proportion blend. As a result, the overall findings offer great application potential in the development of concrete (GCLA). It has been determined that aggregates with a toughness of 14.6% and a hardness of 15.9% are robust. The compressive strength test found that the GCLA has a high strength lightweight concrete of 37.19 MPa and a density of 1845.74 kg/m3. The porous features developed inside the internal structure of GLA have led to GCLA’s less weight compared to conventional concrete.

In this study, the effects of replacing fine aggregate by granulated lead/zinc slag waste (GLZSW) on the thickness of concrete shields against X-ray radiation and on the compressive strength of concrete have been investigated. The fine aggregate was substituted by GLZSW in four percentages: 25%, 50%, 75%, and 100% (by weight). The first aim of the present study was to compare the thicknesses of concretes with GLZSW and control concrete using Lead Equivalent (LE). The second aim was to assess the effects of replacing fine aggregate by GLZSW on the compressive strength of concrete. Results of this study indicated that the compressive strength of mixed concretes increased significantly compared to the control upon replacing fine aggregate by GLZSW; the mixture containing 100% GLZSW had the greatest compressive strength. Further, the inclusion of GLZSW as a substitute for fine aggregate increased the radiation attenuation properties and consequently decreased the thickness of concrete shields in direct proportion to the mixing ratio of GLZSW. The results revealed that concrete mixes containing 100% GLZSW offered the greatest reduction in shield thickness. The study shows that there is a promising future for the use of GLZSW as substitute for fine aggregate in concrete used to shield against X-ray radiation.

The new legislative provisions, regulating the solid fuel trade in Poland, and the resolutions of

provincial assemblies assume, inter alia, a ban on the household use of lignite fuels and solid fuels

produced with its use; this also applies to coal sludge, coal flotation concentrates, and mixtures

produced with their use. These changes will force the producers of these materials to find new

ways and methods of their development, including their modification (mixing with other products

or waste) in order to increase their attractiveness for the commercial power industry. The presented

paper focuses on the analysis of coal sludge, classified as waste (codes 01 04 12 and 01 04 81)

or as a by-product in the production of coals of different types. A preliminary analysis aimed at

presenting changes in quality parameters and based on the mixtures of hard coal sludge (PG SILESIA)

with coal dusts from lignite (pulverized lignite) (LEAG) has been carried out. The analysis

of quality parameters of the discussed mixtures included the determination of the calorific value,

ash content, volatile matter content, moisture content, heavy metal content (Cd, Tl, Hg, Sb, As, Pb,

Cr, Co, Cu, Mn, Ni, and W), and sulfur content. The preliminary analysis has shown that mixing

coal sludge with coal dust from lignite and their granulation allows a product with the desired quality

and physical parameters to be obtained, which is attractive to the commercial power industry.

Compared to coal sludge, granulates made of coal sludge and coal dust from lignite with or without

ground dolomite have a higher sulfur content (in the range of 1–1.4%). However, this is still an

acceptable content for solid fuels in the commercial power industry. Compared to the basic coal

sludge sample, the observed increase in the content of individual toxic components in the mixture

samples is small and it therefore can be concluded that the addition of coal dust from lignite or carbonates

has no significant effect on the total content of the individual elements. The calorific value

is a key parameter determining the usefulness in the power industry. The size of this parameter for

coal sludge in an as received basis is in the range of 9.4–10.6 MJ/kg. In the case of the examined

mixtures of coal sludge with coal dust from lignite, the calorific value significantly increases to

the range of 14.0–14.5 MJ/kg (as received). The obtained values increase the usefulness in the

commercial power industry while, at the same time, the requirements for the combustion of solid

fuels are met to a greater extent. A slight decrease in the calorific value is observed in the case of

granulation with the addition of CaO or carbonates. Taking the analyzed parameters into account,

it can be concluded that the prepared mixtures can be used in the combustion in units with flue gas

desulfurization plants and a nominal thermal power not less than 1 MW. At this stage of work no

cost analysis was carried out.