A 100 km long dense wavelength division multiplexed optical network design with a capacity of 1.28 Tbps is proposed in this paper. The novelty of this work is the use of a dispersion compensating fibre as a Raman amplifier in the S-band for a high-capacity dense wavelength division multiplexing network. The transmission is accomplished auspiciously in the wavelength range from 196 THz to 202. 35THz. The coupling of a Raman amplifier made the realisation of the S-band possible in the network, as the erbium-doped fibre amplifier is competent for amplification in C- and L-bands only. Further, a pump coupler is used for multiple pumping to enlarge the gain spectrum for a high-capacity optical network. The performance analysis of the network is carried out systematically in terms of bit error rate (BER), eye diagram, Q-factor, and optical signal to noise ratio (OSNR). The results demonstrate that the proposed set-up shows adequately low BER, sufficient Q-factor values, wide eye-opening, and commendable OSNR for all receiving channels.