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Abstract

High pressure die casting (HDPC) allows to produce aluminum parts for car industry of complicated shapes in long series. Dies used in this process must be robust enough to withstand long term injection cycling with liquid aluminum alloys, as otherwise their defects are imprinted on the product making them unacceptable. It is expected that nitriding followed by coating deposition (duplex treatment) should protect them in best way and increase intervals between the cleaning/repairing operations. The present experiment covered investigations of the microstructure of the as nitride and deposited with CrAlN coating as well as its shape after foundry tests. The observations were performed with the scanning and transmission electron microscopy (SEM/TEM) method. They showed that the bottom part of this bi-layer is formed by roughly equi-axed Cr2N crystallites, while the upper one with the fine columnar (CrAl)N crystallites. This bi-layers were matched with a set of 7x nano-layers of CrN/(CrAl)N, while at the coating bottom a CrN buffer layer was placed. The foundry run for up to 19 500 cycles denuded most of coated area exposed to fast liquid flow (40 m/s) but left most of bottom part of the coating in the areas exposed to slower flow (7 m/s). The acquired data indicated that the main weakness of this coating was in its porosity present both at the columnar grain boundaries (upper layer) as well as at the bottom of droplets imbedded in it (both layers). They nucleate cracks propagating perpendicularly and the latter at an angle or even parallel to the substrate. The most crack resistant part of the coating turned-out the bottom layer built of roughly equiaxed fine Cr2N crystallites. Even application of this relatively simple duplex protection in the form of CrAlN coating deposited on the nitride substrate helped to extend the die run in the foundry by more than three times.
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Authors and Affiliations

A. Wilczek
1
J. Morgiel
2
ORCID: ORCID
A. Sypień
2
ORCID: ORCID
M. Pomorska
2
ORCID: ORCID
Ł. Rogal
2
ORCID: ORCID

  1. Limatherm S.A., Tarnowska Str. 1, 34-600 Limanowa , Poland
  2. Institute of Metallurgy and Materials Science Polish Academy of Science, 25 Reymonta Str., 30-059 Krakow, Poland
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Abstract

A Cu-1Cr-0.1Zr alloy has been subjected to ECAP processing via route Bc and aging at 250-800°C. Electron BackScatter diffraction (EBSD), Transmission Electron Microscopy (TEM) and X-Ray Diffraction Line Profile Analysis (XRDLPA) techniques have been used to unveil some peculiarities of the grain and subgrain structure with a special emphasis on the comparison of the grain size estimated by the three techniques. For the alloy ECAP processed and aged up to 16 passes, the grain size (from EBSD, 0.2 < d < 5 μm), subgrain size (from TEM, d ~ 0.75 μm) and “apparent” average crystallite size (from XRDLPA, d < 0.25 μm) are manifestly different. The results were compared to the published data and analyzed based on the fundamental aspects of these techniques.
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Authors and Affiliations

K. Abib
1
ORCID: ORCID
B. Alili
1
ORCID: ORCID
T. Baudin
2
ORCID: ORCID
A.-L. Helbert
2
ORCID: ORCID
F. Brisset
2
ORCID: ORCID
L. Litynska-Dobrzynska
3
ORCID: ORCID
P. Zieba
3
ORCID: ORCID
D. Bradai
1
ORCID: ORCID

  1. University Of Sciences And Technology Houari Boumediene, Faculty Of Physics, Bp 32 El Alia, Bab Ezzouar, Algiers, Algeria
  2. University Paris-Saclay, Icmmo, 91405, Orsay, France
  3. Institute Of Meta llurgy And Mat erials Science, Polish Academy Of Sciences, 25 Reymonta Str., 30-059 Krakow, Poland
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Abstract

In this study, NiCrBSi-B4C (wt. %5, %10 ve %15 B4C) powder mixtures are coated on the stainless steel surface of AISI304 by tungsten inert gas (TIG) method. We use optic microscope and scanning electron microscope (SEM) for the coating layer analysis, energy dispersive spectrometry (EDS) for element distribution analysis and X-ray diffractogram (XRD) for the analysis of phase components. The measurements of hardness are determined by the microhardness tester. Based on the results obtained by the examination of microstructure and phases, it has been observed that while B and C elemets are more intense in the middle and upper parts of the coating layer, the parts close to the interface have a higher intensity of Ni and Fe. Moreover, there are phases such as Cr7C3, γ – Ni, CrFeB, Ni3B, CrB ve Fe2B are formed in the coating layer. The increasing ratio of B4C results in increasing on the measurement values of microhardness. The maximum hardness value (430,8 HV0.2) is obtained from the coating layer of S4 sample while the minimum value (366,9 HV0.2) is observed from the NiCrBSi coated sample.
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Bibliography

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Authors and Affiliations

Musa Kiliҫ
1
ORCID: ORCID

  1. Batman University, Faculty of Technology, Department of Manufacturing Engineering, Batman, Turkey
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Abstract

The paper projects the potential of agricultural waste Saraca indica leaf powder (SILP) in biosorbing chromium from aqueous system. The influence of pH, contact time, metal concentration, biomass dosage and particle size on the selectivity of the removal process was investigated. The maximum sorption efficiency of SILP for Cr(lll): 85.23% and Cr(VI): 89.67%was found to be pH dependent giving optimum sorption at pH 6.5 and 2.5 respectively. The adsorption process fitted well to both Freundlich and Langmuir isotherms. Morphological changes observed in Scanning Electron Micrographs ofmetal treated biomass confirm the existence of biosorption phenomenon. Fourier Transform Infra-red Spectrometry confirms that amino acid-Cr interactions contribute a significant role in the biosorption of chromium using target leafpowder. The successful applications of easily abundant agricultural waste SILP, as a biosorbent have potential for a low technological pretreatment step, prior to economically not viable high-tech chemical treatments for the removal of Cr from water bodies.
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Authors and Affiliations

Pritee Goyal
Parul Sharma
Shalini Srivastava
M.M. Srivastava
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Abstract

A thermo-insulating moulding sand with a binder made of aluminosilicate microspheres with organic binder was subjected to testing. The aim of the analysis was to determine selected technological properties of the developed compounds. Compressive strength, friability and gas permeability were determined. The binder content was changed within a range of 5÷20 wt% with a 5% step. The applied matrix is characterized by good thermo-insulating properties and a small size of grains, while synthetic organic binder has favourable functional properties, among which the most noteworthy are the extended life and setting time, good rheological properties as well as high resistance to chemical agents. The intended use of the compound is the casting of 3D CRS (Composite Reinforced Skeletons), which are characterized by a well-developed heat transfer surface area, good absorption of impact energy, low mass and a target thickness of connectors within a range of 1.5÷3 mm. The construction of 3D CRS castings is an original concept developed by the employees of the Department of Foundry Engineering at the Silesian University of Technology.

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Authors and Affiliations

K. Stec
Marian Cholewa
Ł. Kozakiewicz
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Abstract

This paper presents the possibility of improving the scratch resistance of the AZ91 magnesium alloy by applying a WCCoCr coating using the Air Plasma Spraying (APS) method. The coating thickness ranged from 140 to 160 m. Microstructural studies of the AZ91 magnesium alloy were performed. The chemical composition of the WCCoCr powder was investigated. The quality of the bond at the substrate–coating interface was assessed and a microanalysis of the chemical composition of the coating was conducted. The scratch resistance of the AZ91 alloy and the WCCoCr coating was determined. The scratch resistance of the WCCoCr powder-based coating is much higher than the AZ91 alloy, as confirmed by scratch geometry measurements. The scratch width in the coating was almost three times smaller compared to the scratch in the substrate. Observations of the substrate–coating interface in the scratch area indicate no discontinuities. The absence of microcracks and delamination at the transition of the scratch from the substrate to the coating indicates good adhesion. On the basis of the study, it was found that there was great potential to use the WCCoCr powder coating to improve the abrasion resistance of castings made from the AZ91 alloy.
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Bibliography

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[9] Chen, H. & Alpas A.T. (2000). Sliding wear map for the magnesium alloy Mg-9Al-0.9Zn (AZ91). Wear. 246(1-2), 106-116. DOI: 10.1016/S0043-1648(00)00495-6.
[10] Walczak, M., Caban, J. & Pliżga, P. (2015). Tribological characteristic of magnesium alloys used in means of transport. TTS Technika Transportu Szynowego. 22(12), 1614-1617.
[11] Parco, M., Zhao, L., Zwick, J., Bobzin, K. & Lugscheider, E. (2007). Investigation of particle flattening behaviour and bonding mechanisms of APS sprayed coatings on magnesium alloys. Surface and Coating Technology. 201(14), 6290-6296. DOI: 10.1016/j.surfcoat.2006.11.034.
[12] Morelli, S., Rombol`a, G., Bolelli, G., Lopresti, M., Puddu, P, Boccaleri, E., Seralessandri, L., Palin, L., Testa, V., Milanesio, M. & Lusvarghi, L. (2022). Hard ultralight systems by thermal spray deposition of WC-CoCr onto AZ31 magnesium alloy. Surface and Coating Technology. 451, 129056 1-26. DOI.org/10.1016/j.surfcoat.2022.129056.
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Authors and Affiliations

Marek Mróz
1
ORCID: ORCID
Sylwia Olszewska
1
ORCID: ORCID
Patryk Rąb
1
ORCID: ORCID

  1. Rzeszow University of Technology, Poland
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Abstract

This paper presents the results of diagnostic examinations conducted on the coils of super-heaters made of 10CrMo9‒10 steel that were operated in industrial conditions at 480°C for 130 thousand hours. The tube was exposed in a coal-fired boiler. The chemical and phase composition of the oxide/deposit layers formed on both sides of the tube walls (outside – flue-gas side and inside – steam side) and their sequence was examined using optical microscopy, scanning electron microscopy with electron backscatter diffraction and energy-dispersive X-ray spectroscopy, and X-ray diffraction. The changes in the mechanical properties caused by corrosion and aging processes were concluded from the hardness measurements. In addition, the nature of cracks in the oxide layers caused by pressing a Vickers indenter was determined. The results of these examinations have shown a high degradation of steel on the flue-gas inflow side and identified the main corrosion products and mechanisms.
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Bibliography

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Authors and Affiliations

Monika Gwoździk
1
Christiane Ullrich
2
Christian Schimpf
2
David Rafaja
2
Sławomir Kulesza
3
Mirosław Bramowicz
3

  1. Czestochowa University of Technology, ul. Dabrowskiego 69, 42-201 Czestochowa, Poland
  2. TU Bergakademie Freiberg, Akademiestraße 6, 09599 Freiberg, Germany
  3. University of Warmia and Mazury in Olsztyn, ul. Michała Oczapowskiego 2, 10-719 Olsztyn, Poland
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Abstract

The methods of severe plastic deformation (SPD) of metals and metal alloys are very attractive due to the possibility of refinement of the grains to nanometric sizes, which facilitates obtaining high mechanical properties. This study investigated the influence of SPD in the process of hydrostatic extrusion (HE) on the anisotropy of the mechanical properties of the CuCrZr copper alloy. The method of HE leads to the formation of a characteristic microstructure in deformed materials, which can determine their potential applications. On the longitudinal sections of the extruded bars, a strong morphological texture is observed, manifested by elongated grains in the direction of extrusion. In the transverse direction, these grains are visible as equiaxed. The anisotropy of properties was mainly determined based on the analysis of the static mini-sample static tensile test and the dynamic impact test. The obtained results were correlated with microstructural observations. In the study, three different degrees of deformation were applied at the level necessary to refine the grain size to the ultrafine-grained level. Regardless of the applied degree of deformation, the effect of the formation of a strong morphological texture was demonstrated, as a result of which there is a clear difference between the mechanical properties depending on the test direction, both by the static and dynamic method. The obtained results allow for the identification of the characteristic structure formed during the HE process and the more effective use of the CuCrZr copper alloy in applications.
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Authors and Affiliations

Sylwia Przybysz
1
Mariusz Kulczyk
1
ORCID: ORCID
Jacek Skiba
1
Monika Skorupska
1

  1. Institute of High Pressure Physics of the Polish Academy of Sciences, Warszawa, Poland
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Abstract

Oncological surgery is the primary treatment for gynecological malignancies and is inseparably linked with anesthesia. The modern approach to interdisciplinary and multidisciplinary perioperative care in gynecologic oncological patients improves the outcome. This paper presents a review of perioperative management of patients with gynecologic oncology related to enhanced recovery after surgery and cytor-eductive surgery with hyperthermic intraperitoneal chemotherapy. We performed a literature search on MEDLINE, EMBASE, Google Scholar, the Cochrane Central Register of Controlled Trials, and Clinical Trials. The database search focused on selected topics related to perioperative gynecological oncology care. The authors also contributed through individual, independent literature searches.
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Authors and Affiliations

Paweł Krawczyk
1
Rafał Baran
2
Dominika Trojnarska
3
Robert Jach
3
Janusz Andres
1

  1. Department of Anesthesiology and Intensive Care Medicine, Jagiellonian University Medical College, Kraków, Poland
  2. Department of Gynecological Endocrinology and Gynecology, University Hospital, Kraków, Poland
  3. Department of Obstetrics and Gynecology, Jagiellonian University Medical College, Kraków, Poland
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Abstract

The 22Cr25NiWCoCu austenitic stainless steel was developed by AB Sandvik Material Technology in Sweden. Due to its high creep strength and good corrosion resistance, this material is well suited for use in superheaters in advanced coal-fired power boilers as well as in other types of steam boilers using various types of fuel. The examined material was subject to long-term ageing for the time of annealing up to 20 000 h at 700 and 750°C. Precipitation processes and microstructure stability as-received and after ageing were investigated. Examination of the microstructure was conducted using scanning electron microscopy. The identification of secondary phases was carried out by X-ray phase composition.
Using the results of the investigations of precipitation processes in the microstructure, both within the grains and at the grain boundaries, their statistical analysis was carried out. To illustrate this impact, the following parameters were used: surface area and equivalent diameter of precipitates. Based on the surface area measurements, the percentage of the phase in the reviewed photo’s total area was calculated.
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Authors and Affiliations

M. Sroka
1
ORCID: ORCID
A. Zieliński
2
ORCID: ORCID
T. Puszczało
1 3
ORCID: ORCID
K. Sówka
1 3
ORCID: ORCID
B. Hadzima
4

  1. Silesian University of Technology, Department of Engineering Materials and Biomaterials, S. Konarskiego 18A, 44-100 Gliwice, Poland
  2. Łukasiewicz Research Network – Institute for Ferrous Metallurgy, K. Miarki 12-14, 44-100 Gliwice, Poland
  3. ZRE, ul. Gen. Jankego 13, 40-615 Katowice, Poland
  4. University of Žilina, Univerzitná 8215/1, 010 26 Žilina, Slovakia
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Abstract

In this study, Ni20Cr coatings were obtained by cold spraying on an aluminum alloy 7075 substrate. The obtained coatings were characterized by a uniform microstructure and low porosity. The sprayed coating has the same phase composition as the powder used. Next, the cold sprayed coatings were heat treated using a TRUMPF TLF 6000 TURBO (4 kW) CO2 laser. The laser surface melting of the coatings resulted in the formation of a columnar structure and an improvement in their mechanical properties. The Ni20Cr cold sprayed coatings after additional laser melting showed lower porosity and an increase in microhardness and Young`s modulus.
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Bibliography

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Authors and Affiliations

D. Soboń
1
ORCID: ORCID

  1. Kielce University of Technology, 7 Tysiąclecia Państwa Polskiego Av., 25-314 Kielce, Poland
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Abstract

Gaseous nitriding of binary Ni-Cr solid-solution alloys was studied at 1125ºC over the range 1 to 6000 bar of N2-pressure. At the specified temperature the nitriding response of the Ni-Cr alloys depends on the Cr-content in the initial alloy and activity (fugacity) of nitrogen at the gas/metal interface. Transition from cubic δ-CrN to hexagonal β-Cr2N precipitation occurs within the reaction zone after nitrogenization at 1125ºC under nitrogen pressure 100-6000 bar when chromium content in the initial alloy is 28 at. % or higher. It was found that a ternary phase, π (Cr12.8Ni7.2N4.0) is formed inside the Ni32Cr alloy upon cooling in nitrogen after nitriding at 1125ºC and 1 bar of N2. Experimental evidence is presented that π-phase is involved in peritectoid relations with β-Cr2N and γ-(Ni-Cr) solid solution. It was also demonstrated that nitriding behaviour of the Ni-Cr alloy can be rationalized using pertinent phase diagram information, but, in some cases, effect of mechanical stresses induced upon the internal precipitation can vitiate this prediction.
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Authors and Affiliations

A. Kodentsov
1
ORCID: ORCID
C. Cserháti
2

  1. Mat-Tech BV, Development & Testing, Son, The Netherlands
  2. University of Debrecen Hungary Faculty of Sciences and Technology, Department of Solid State Physics, Hungary
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Abstract

The heavy metal content is one of the criteria for foundry dust commercial use. To assess the possibility of foundry dust use, it is necessary to analyze its composition, including the content of basic heavy metals, and its mechanical properties. The paper presents the results of research on foundry dust from one of the Polish foundries. The aim of the study was to assess the waste management based on its composition and content of heavy metals. Dust samples were taken from one of the Polish foundries, producing iron and steel castings. Samples were taken from several places in the foundry, i.e. from electric furnace dust collectors, shock grating unit, transport of moulding sands unit, pneumatic blast cabinet units and the regeneration of spent foundry sand units. Samples were taken twice from each place at the turn of 2017–2018. The total content of heavy metals such as Cd, Pb, Cu, Zn, Cr, Ni, Mn, and Fe for recovery and additionally Hg as environmental pollution was analyzed. Based on the results of the research, it was found that the dust from foundry furnaces and pneumatic cleaners can be used in metallurgy due to a high percentage of iron. It was found that the dust from casting cleaning, transport and regeneration department can be used in the cement or construction industry. In addition, an assessment of the mercury content showed that the re-use of this dust would not cause an environmental hazard. It was found that the profitability of foundry dust use depends on the stability of its composition and requires testing for each batch of dusts.

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Authors and Affiliations

Marta Bożym
ORCID: ORCID
Beata Klojzy-Karczmarczyk
ORCID: ORCID
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Abstract

This article presents the results of a research on the behavior of NiCrAlY coating obtained by the LENS method on austenitic stainless steel type 316L under long-term annealing conditions at 1000°C for 25, 100 and 250 hours. The morphology of the NiCrAlY layer as a function of annealing time and temperature was characterized. The chemical composition and distribution of alloying elements were eval-uated using scanning microscopy and micro-area chemical composition analysis. It was revealed that NiCrAlY coatings deposited by LENS method are characterized by good metallurgical quality. The long-term annealing of the NiCrAlY coating led to microstructural changes in the form of the disappearance of the original dendritic structure and the formation of a solid solution of nickel with chromium and a small amount of aluminum, as well as chromium α-Cr precipitates and Ni-Y-type phases. The effect of increasing iron concentration in the coating due to diffusion-to-core processes was also found
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Bibliography

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[5] Zhu, C., Li, P., Javed, A., Liang, G.Y. & Xiao, P. (2012). An investigation on the microstructure and oxidation behavior of laser remelted air plasma sprayed thermal barrier coatings. Surfaces and Coatings Technology 206(18), 3739-3746. DOI: 10.1016/j.surfcoat.2012.03.026.
[6] Ghasemi, R., Razavi, R.S., Mozafarinia, R., Jamali, H., Oghaz, M.H. & Pidani, R.A. (2014). The influence of laser treatment on hot corrosion behavior of plasma-sprayed nanostructured yttria stabilized zirconia thermal barrier coatings. Journal of European Ceramic Society. 34(8), 2013-2021. DOI: 10.1016/j.jeurceramsoc.2014.01.031.
[7] Nowotny, S., Berger, L.-M. & Spatzier, J. (2014). Coatings by laser cladding. Comprehensive hard materials. Editors: V.K. Sarin. Elsevier. 507-525. DOI: 10.1016/B978-0-08-096527-7.00018-0.
[8] Moskal, G., Niemiec, D., Chmiela, B., Kałamarz, P., Durejko, T., Ziętala, M. & Czujko, T. (2020). Microstructural characterization of laser-cladded NiCrAlY coatings on Inconel 625 Ni-based superalloy and 316L stainless steel. Surface & Coatings Technology 387, 125317. DOI: 10.1016/j.surfcoat.- 2019.125317.
[9] Ma, K. Tang, F., & Schoenung, J.M. (2010). Investigation into the effects of Fe additions on the equilibrium phase compositions, phase fractions and phase stabilities in the Ni-Cr-Al system. Acta Materialia. 58(5), 1518-1529. DOI: 10.1016/j.actamat.2009.10.059.
[10] Zhang, P., Li, X., Moverare, J. & Peng, R. (2019). The iron effect on oxidation and interdiffusion behaviour in MCrAlX coated Ni-base superalloys. Materials & Design. 166(15), 107599. DOI: 10.1016/j.matdes.2019.107599.
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Authors and Affiliations

K.K. Szymański
1
ORCID: ORCID

  1. Silesian Technical University of Technology, Faculty of Materials Science and Engineering, Department of Metallurgy and Recycling, ul. Krasińskiego 8, 40-019 Katowice, Poland
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Abstract

In this work, we present an extensive investigation of the effect of Al2O3 decoration on the morphological, structural and opto-electronic properties of a porous Si (Sip)/Cr2O3 composite. The Sip layers were prepared by the anodization method. Al2O3 and Cr2O3 thin films were deposited by physical vapour deposition. The morphological and micro-structural properties of Sip/Cr2O3/Al2O3 were studied using the scanning electron microscope, energy dispersive X-ray spectroscopy and X-ray diffraction techniques. It was found that Al2O3 decoration with different concentration strongly affects the Sip/Cr2O3 microstructure mainly at the level of porosity. Variable angle spectroscopic ellipsometry demonstrates a strong correlation between optical constants (n and k) of Sip/Cr2O3/Al2O3 and microstructure properties. Dielectric properties of Sip/Cr2O3/Al2O3 such as electrical conductivity and conduction mechanism were explored using impedance spectroscopy over the temperature interval ranging from 340 to 410°C. A semiconductor to the metallic transition has been observed at high frequency.

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Authors and Affiliations

M. Ghrib
B. Tlili
M. Razeg
R. Ouertani
M. Gaidi
H. Ezzaouia
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Abstract

The integration of optical fibre communication with multiple input multiple output-non-orthogonal multiple access (MIMO-NOMA) waveforms in cognitive radio (CR) systems is examined in this study. The proposed system leverages the advantages of optical fibre, including high bandwidth and immunity to electromagnetic interference to facilitate the transmission and reception of MIMO-NOMA signals in a CR environment. Moreover, MIMO-NOMA signal was detected and analysed by the hybrid-discrete cosine transform-Welch (H-DCT-W) method. Based on the modes results, a detection probability greater than 0.96%, a false alarm probability equal to 0.06, and a global system error probability equal to 0.09% were obtained with a signal-to-noise ratio (SNR) less than 0 dB, while maintaining a simple level of complexity. The results obtained in this paper indicate the potential of the optical fibre-based MIMO-NOMA system based on H-DCT-W technology in CR networks. Therefore, its suitability for practical CR applications is demonstrated by the improvements obtained in false alarms, detection probability, and error rates at low levels of SNR. This study contributes to the development of efficient and reliable wireless communication systems by linking cooperation and synergy concerning MIMO-NOMA, optical fibres, as well as the proposed detection technique (H-DCT-W).
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Authors and Affiliations

Zeyad T. Yaseen
1
Waleed Algriree
2

  1. Department of Medical Device Technology Engineering, Al Mustaqbal University, Babylon, Iraq
  2. Department of Electrical and Electronic Engineering, Faculty of Engineering, University Putra Malaysia, Serdang 43400, Selangor, Malaysia
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Abstract

Mating electrodes made of copper alloys are commonly used for welding galvanized steel sheets used in the production of car bodies. These alloys are characterized by high mechanical properties, a high level of electrical and thermal conductivity as well as the stability of these properties under changing conditions of current, thermal and mechanical load. Much careful attention was paid to the essence of the ongoing structural changes as well as to the mechanical properties in the welding process (RSW – Resistant Spot Welding) of steel sheets, including high-strength ones. There is a lack of research on structural changes and the related mechanical properties occurring in welding electrodes made of copper alloys caused by the welding process.
This study is devoted to these issues and contains a critical review of the research results enabling a better understanding of the relationships between the structure and properties of welding electrodes caused by the cyclic welding process. In order to illustrate the phenomena occurring during the welding process, both in the material to be welded and in the tip electrodes, hardness and structural tests were carried out on electrode samples before and after their exploitation. The data collected in the article supplements a certain lack of information in the literature regarding the microstructural aspects of the welding process of galvanized steel sheets for the production of car bodies. The conducted research may be the starting point for the search for more effective materials for the tip electrodes.
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Authors and Affiliations

Z. Rdzawski
1
ORCID: ORCID
P. Kwaśniewski
2
ORCID: ORCID
W. Głuchowski
1
ORCID: ORCID
M. Łagoda
1
ORCID: ORCID
M. Maleta
1
ORCID: ORCID
S. Boczkal
3
ORCID: ORCID
K. Franczak
2
ORCID: ORCID

  1. Łukasiewicz Research Network – Institute of Non-Ferrous Metals, 5 Sowińskiego Street, 44-100 Gliwice, Poland
  2. AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow, Poland
  3. Łukasiewicz Research Network – Institute of Non-Ferrous Metals, Light Metals Division, 19 Piłsudskiego Street, 32-050 Skawina, Poland
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Abstract

This study fabricated a WC/T-800 cermet coating layer with Co-Mo-Cr (T-800) powder and WC powder using laser cladding, and analyzed its microstructure, hardness and wear properties. For comparison, casted bulk T-800 was used. Laser cladded ­WC/T-800 cermet coating layer showed circular WC phases in the Co matrix, and dendritic laves phases. The average laves phase size in the cermet coating layer and bulk T-800 measured as 7.9 µm and 60.6 µm, respectively, indicating that the cermet coating layer had a relatively finer laves phase. Upon conducting a wear test, the cermet coating layer added with WC showed better wear resistance. In the case of laser cladded WC/T-800 cermet coating layer, abrasion wear was observed; on the contrary, the bulk T-800 showed pulled out laves phases. Based on the above findings, the WC/T-800 cermet coating layer using laser cladding and the relationship between its microstructure and wear behavior were discussed.
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Authors and Affiliations

Kyoung-Wook Kim
1
Young-Kyun Kim
1
ORCID: ORCID
Sun-Hong Park
2
Kee-Ahn Lee
1
ORCID: ORCID

  1. Inha University, Dept. Mater. Sci. Eng., Incheon 22212, Republic of Korea
  2. POSCO Technical Research Laboratories, Gwangyang 57807, Republic of Korea
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Abstract

The effects of the sintering holding time and cooling rate on the microstructure and mechanical properties of nanocrystalline Fe-Cr-C alloy were investigated. Nanocrystalline Fe-1.5Cr-1C (wt.%) alloy was fabricated by mechanical alloying and spark plasma sintering. Different process conditions were applied to fabricate the sintered samples. The phase fraction and grain size were measured using X-ray powder diffraction and confirmed by electron backscatter diffraction. The stability and volume fraction of the austenite phase, which could affect the mechanical properties of the Fe-based alloy, were calculated using an empirical equation. The sample names consist of a number and a letter, which correspond to the holding time and cooling method, respectively. For the 0A, 0W, 10A, and 10W samples, the volume fraction was measured at 5.56, 44.95, 6.15, and 61.44 vol.%. To evaluate the mechanical properties, the hardness of 0A, 0W, 10A, and 10W samples were measured as 44.6, 63.1, 42.5, and 53.8 HRC. These results show that there is a difference in carbon diffusion and solubility depending on the sintering holding time and cooling rate.
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Authors and Affiliations

Gwanghun Kim
1
ORCID: ORCID
Junhyub Jeon
1
ORCID: ORCID
Namhyuk Seo
1
ORCID: ORCID
Seunggyu Choi
1
Min-Suk Oh
1
ORCID: ORCID
Seung Bae Son
1
ORCID: ORCID
Seok-Jae Lee
1
ORCID: ORCID

  1. Jeonbuk National University, Division of Advanced Materials Engineering, 567 Baekje-daero, Deokjin-gu, Jeonju, 54896, Republic of Korea
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Abstract

In this study, the effect of the addition of ZrO2 and Al2O3 ceramic powders to Cu-Mo-Cr alloy was studied by examining the physical properties of the composite material. The ceramic additives were selected based on the thermodynamic stability calculation of the Cu-Mo-Cr alloys. Elemental powders, in the ratio Cu:Mo:Cr = 60:30:10 (wt.%), and approximately 0-1.2 wt.% of ZrO2 and Al2O3 were mixed, and a green compact was formed by pressing the mixture under 186 MPa pressure and sintering at 1250°C for 5 h. The raw powders were evenly dispersed in the mixed powder, as observed by scanning electron microscopy. After sintering, the microstructures, densities, electrical conductivities, and hardness of the composites were evaluated. We found that the addition of ZrO2 and Al2O3 increased the hardness and decreased the electrical conductivity and density of the composites.
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Authors and Affiliations

Yeong-Woo Cho
1 2
ORCID: ORCID
Jae-Jin Sim
1 2
ORCID: ORCID
Sung-Gue Heo
1 3
ORCID: ORCID
Hyun-Chul Kim
1 3
Yong-Kwan Lee
1 2
ORCID: ORCID
Jong-Soo Byeon
1 2
ORCID: ORCID
Yong-Tak Lee
1 2
ORCID: ORCID
Kee-Ahn Lee
2
ORCID: ORCID
Seok-Jun Seo
1
ORCID: ORCID
Kyoung-Tae Park
1
ORCID: ORCID

  1. Korea Institute for Rare Metals, Korea Institute of Industrial Technology, 7-50 Songdo-dong Yeonsoo-gu, Incheon 21999, Korea
  2. Inha University, Department of Advanced Materials Engineering, Incheon 22212, Korea
  3. Korea University, Department of Materials Science and Engineering, Seoul 02841, Korea
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Abstract

The aim of this paper is to present the procedure test for calibration and validation of the numerical model for X22CrMoV12-1 steel multilayer welding. On the real multilayer weld was described how to arrange the whole experiment in order to obtain not only relevant input data but also verification data. Tests on a specially prepared specimen, welded with 8 beads in 4 layers, allows to determine the actual geometry of the single welded beads, registration of welding thermal cycles and the hardness distribution in successively deposited beads together with determining the heat influence of subsequent layers. The results of the real welding tests were compared with the results obtained from the numerical simulations and extended by the calculated stresses and distortions distributions of the tested specimen. A new, improved hardness prediction algorithm for high-alloy martensitic and bainitic steels was also proposed.

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Authors and Affiliations

T. Kik
ORCID: ORCID
J. Moravec
ORCID: ORCID
I. Novakova
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Abstract

We investigated the effect of Cr thin film deposition on the thermal stability and corrosion resistance of hot-dip aluminized steel. A high-quality Cr thin film was deposited on the surface of the Al-9 wt. % Si-coated steel sheets by physical vapor deposition. When the Al-Si coated steel sheets were exposed to a high temperature of 500℃, Fe from the steel substrate diffused into the Al-Si coating layer resulting in discoloration. However, the highly heat-resistant Cr thin film deposited on the Al-Si coating prevented diffusion and surface exposure of Fe, improving the heat and corrosion resistances of the Al-Si alloy coated steel sheet.
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Authors and Affiliations

Jae-Hyeon Kim
1
Jung-Ha Lee
2
Seung-Beop Lee
2
Sung-Jin Kim
3
ORCID: ORCID
Min-Suk Oh
1
ORCID: ORCID

  1. Jeonbuk National University, Division of Advanced Materials Engineering And Research Center For Advanced Materials Development, Jeonju, Republic of Korea
  2. Jeonbuk National University, School of International Engineering And Science, Jeonju, Republic of Korea
  3. Sunchon National University, Department of Advanced Materials Engineering, Sunchon, Republic of Korea
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Abstract

The lack of room-temperature ductility of high-strength TiAl-based alloys called for complicated high temperature processing limiting their application areas. Introduction of additive manufacturing (AM) methods allowed to circumvent this disadvantage, but entailed microstructure refinement affecting, among the others, their oxidation resistance. The dry-air high temperature oxidation processing of TiAl-based alloys is relatively well covered for coarse grained materials, but to what extent the TiAl alloys are affected by the changes caused by the AM remains to be found out. Additionally, the role of nitrogen during these processes was to large extent omitted in previous works. Within the present experiment, the mould cast (MC) and the electron beam melted (EBM) Ti-48Al-2Nb-0.7Cr-0.3Si (at. %) RNT650 alloys were dry-air oxidized at 650°C for 1000 h. The TEM/EDS investigations allowed to confirm that the scale formed during such treatment consists of the layers occupied predominantly by TiO2+Al2O3/TiO2/Al2O3 sequence. Additionally, it was shown that N diffuses to the sub-scale and reacts with the substrate forming two distinct discontinuous sub-layers of α2-Ti3Al(N) and TiN. The scale over EBM was noticeably less porous and nitrogen penetration of the substrate was more extensive, while the MC showed higher susceptibility to local sub-scale oxidation.
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Authors and Affiliations

J. Morgiel
1
ORCID: ORCID
T. Dudziak
2
ORCID: ORCID
L. Maj
1
ORCID: ORCID
A. Kirchner
3
M. Pomorska
1
ORCID: ORCID
B. Klöden
3
T. Weissgärber
3
D. Toboła
2
ORCID: ORCID

  1. Polish Academy of Science, Institute of Metallurgy and Materials Science, 25 Reymonta Str., 30-059-Kraków, Poland
  2. Łukasiewicz Research Network, Kraków Institute of Technology, 73 Zakopianska Str, 30-418 Kraków, Poland
  3. Fraunhofer-Institut für Fertigungstechnik und Angewandte Materialforschung IFAM, Institutsteil Dresden Winterbergstrasse 28, 01277 Dresden, Germany

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